WebMO Job Summary

124366: 11. m,p-dinitromethyl benzoate, Optimize + Vib Freq - Gaussian

Calculated Quantities

Expand all

Overview

Quantity Value
Route #N M062X/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Stoichiometry C8H6N2O6
Symmetry C1
Basis 6-311+G(2d,p)
RM062X Energy -869.047492421 Hartree
ZPE 0.150267 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -868.883488 Hartree
Enthalpy -868.882544 Hartree
Free Energy -868.939300 Hartree
Cv 49.006 cal/mol-K
Entropy 119.454 cal/mol-K
Dipole Moment 7.8143 Debye
Server batch (126805)
CPU time 58603.4 sec

Geometry Sequence Energies

Step Energy  
0 -869.046205505  
1 -869.043221867  
2 -869.046714278  
3 -869.043979614  
4 -869.047395252  
5 -869.047085235  
6 -869.047447794  
7 -869.045752160  
8 -869.047461515  
9 -869.047471719  
10 -869.047492099  
11 -869.047492041  
12 -869.047492421  
13 -869.047492421  
14 -869.047492421  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1.08833 0.03630278117
b 0.31039 0.01035349595
c 0.25047 0.00835477989

Partial Charges

Atom Symbol Charge
1 C -0.240629  
2 O -0.295678  
3 C 0.557716  
4 C 0.493075  
5 C -0.280138  
6 C -0.072934  
7 C 0.014889  
8 C 0.037327  
9 C -0.520043  
10 H 0.172184  
11 H 0.170842  
12 N 0.082282  
13 O -0.110695  
14 O -0.126751  
15 N 0.068418  
16 O -0.132032  
17 O -0.095009  
18 H 0.206919  
19 O -0.448129  
20 H 0.165449  
21 H 0.176561  
22 H 0.176377  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 43.2453 0.0792
2 A 47.2141 0.6387
3 A 66.1210 1.6073
4 A 103.7160 0.1140
5 A 116.3152 0.2289
6 A 131.8122 1.8391
7 A 160.4384 4.6014
8 A 188.0548 0.5075
9 A 208.8355 0.7499
10 A 243.0605 4.5437
11 A 260.1190 3.3282
12 A 279.2726 0.3191
13 A 349.2337 17.6700
14 A 361.3178 4.6722
15 A 392.8203 0.5355
16 A 434.2738 0.9688
17 A 494.8823 1.3477
18 A 512.4523 14.1959
19 A 584.1490 3.2185
20 A 631.8539 6.5396
21 A 678.4174 4.7421
22 A 711.4295 4.4850
23 A 756.7120 14.1154
24 A 774.1532 56.4083
25 A 807.2068 1.0047
26 A 813.2421 9.9097
27 A 850.2204 35.5785
28 A 888.3318 51.5368
29 A 892.1799 11.9771
30 A 935.4840 1.2272
31 A 975.4705 8.8019
32 A 1004.8600 1.5317
33 A 1043.7122 20.4534
34 A 1103.1303 0.2055
35 A 1151.9414 11.5391
36 A 1179.6863 4.4370
37 A 1189.4832 1.1002
38 A 1207.0877 95.1191
39 A 1239.6880 48.4928
40 A 1283.0691 41.8761
41 A 1337.5184 513.1083
42 A 1348.7482 29.9876
43 A 1455.5752 83.0970
44 A 1469.9340 124.5963
45 A 1482.4666 207.9884
46 A 1491.6368 5.5185
47 A 1495.8045 11.7833
48 A 1505.9462 11.4772
49 A 1541.7998 8.9068
50 A 1666.4811 44.3940
51 A 1678.1947 142.1150
52 A 1704.4125 475.8743
53 A 1715.2720 59.4097
54 A 1839.8945 265.3048
55 A 3088.3809 22.7472
56 A 3172.7519 7.3879
57 A 3190.3428 4.1969
58 A 3209.2176 2.7791
59 A 3231.7242 7.3450
60 A 3238.8570 14.9684
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

I think that all right-thinking people in this country are sick and tired of being told that ordinary, decent people are fed up in this country with being sick and tired. I'm certainly not! But I'm sick and tired of being told that I am! -- Monty Python