WebMO Job Summary

124550: N,N'-dimesitylethanediimine, Opt + VibFreq MaxIterations - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT=(maxcycle=100) FREQ Geom=Connectivity
Stoichiometry C20H24N2
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -886.338479206 Hartree
ZPE 0.387337 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -885.927496 Hartree
Enthalpy -885.926552 Hartree
Free Energy -886.006863 Hartree
Cv 87.129 cal/mol-K
Entropy 169.029 cal/mol-K
Dipole Moment 0.0678 Debye
Server batch (126989)
CPU time 283989.7 sec

Geometry Sequence Energies

Step Energy  
0 -886.336402463  
1 -886.338448427  
2 -886.338455943  
3 -886.338462265  
4 -886.338463464  
5 -886.338465158  
6 -886.338466719  
7 -886.338470476  
8 -886.338474776  
9 -886.338477484  
10 -886.338478260  
11 -886.338478673  
12 -886.338479047  
13 -886.338479158  
14 -886.338479193  
15 -886.338479203  
16 -886.338479206  
17 -886.338479206  
18 -886.338479206  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 0.81663 0.02723984471
b 0.09278 0.00309480768
c 0.09022 0.00300941527

Partial Charges

Atom Symbol Charge
1 C -0.529361  
2 C 0.508249  
3 C -0.096572  
4 C 0.381377  
5 C -0.630762  
6 C 0.682617  
7 C -0.532225  
8 H 0.074756  
9 C -0.422509  
10 H 0.118591  
11 H 0.124085  
12 H 0.139518  
13 H 0.073421  
14 C -0.532086  
15 H 0.142005  
16 H 0.137187  
17 H 0.123479  
18 N -0.141594  
19 C -0.115389  
20 C -0.114388  
21 N -0.141781  
22 C -0.086466  
23 C 0.546449  
24 C -0.442079  
25 C 0.611048  
26 C -0.708574  
27 C 0.384956  
28 C -0.531736  
29 H 0.137285  
30 H 0.123455  
31 H 0.142138  
32 H 0.073183  
33 C -0.416870  
34 H 0.128235  
35 H 0.139310  
36 H 0.116045  
37 H 0.074773  
38 C -0.529568  
39 H 0.145365  
40 H 0.132749  
41 H 0.112882  
42 H 0.103914  
43 H 0.103874  
44 H 0.145384  
45 H 0.132828  
46 H 0.112801  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 19.5653 0.0022
2 A 24.0462 0.0598
3 A 27.0419 1.5290
4 A 35.0057 0.1180
5 A 37.1237 0.1534
6 A 59.0337 6.9452
7 A 60.2618 0.0998
8 A 105.9036 17.3962
9 A 136.6581 0.4558
10 A 144.9191 0.4887
11 A 148.4956 0.2602
12 A 152.8300 3.3753
13 A 156.7273 0.8293
14 A 176.9330 5.5477
15 A 189.2378 2.7882
16 A 191.9220 0.0355
17 A 215.7815 12.8684
18 A 227.9429 0.1305
19 A 228.7564 0.8620
20 A 246.8640 3.8223
21 A 275.2345 0.1177
22 A 277.0660 0.2959
23 A 302.0367 0.5234
24 A 318.8327 19.1374
25 A 323.7082 1.1062
26 A 386.9590 9.7940
27 A 401.0649 5.3578
28 A 429.4403 0.0022
29 A 430.7506 1.0424
30 A 509.8965 0.9247
31 A 513.8290 0.4351
32 A 520.2622 14.0836
33 A 521.6191 2.7131
34 A 538.4739 8.2192
35 A 544.0574 0.0446
36 A 572.5872 0.6464
37 A 573.8553 0.2045
38 A 584.4431 0.2599
39 A 599.6179 2.9929
40 A 604.9772 3.7278
41 A 625.4393 3.2779
42 A 750.4178 6.5538
43 A 760.1958 2.1992
44 A 794.1864 11.9808
45 A 834.0613 0.0089
46 A 872.7211 12.8171
47 A 873.6508 30.2257
48 A 898.3436 0.2344
49 A 898.7450 0.2464
50 A 941.5981 7.6445
51 A 950.8806 5.1980
52 A 973.0329 0.9518
53 A 973.4644 0.4455
54 A 982.5768 3.4000
55 A 1019.4384 1.1020
56 A 1028.6073 0.4719
57 A 1029.9212 8.6734
58 A 1033.2064 0.9935
59 A 1034.2366 1.6953
60 A 1052.2585 0.1171
61 A 1053.3750 1.0687
62 A 1059.8587 1.4490
63 A 1060.0103 0.0479
64 A 1063.0842 8.2492
65 A 1063.3060 7.1167
66 A 1064.6733 1.9726
67 A 1064.8302 5.9251
68 A 1164.9197 22.5842
69 A 1170.9677 0.1625
70 A 1174.7650 0.1208
71 A 1226.4854 44.9228
72 A 1231.6194 0.0461
73 A 1280.0412 0.8372
74 A 1280.9284 0.0041
75 A 1297.2136 0.5726
76 A 1300.1114 0.3124
77 A 1316.7119 2.4789
78 A 1319.1839 3.0884
79 A 1323.5613 5.7998
80 A 1377.2155 0.0061
81 A 1414.3988 1.1165
82 A 1414.4708 0.4068
83 A 1415.7403 1.7665
84 A 1415.8396 0.9780
85 A 1418.1697 0.1232
86 A 1418.4441 0.3779
87 A 1443.3510 0.8652
88 A 1444.2155 0.1413
89 A 1457.5343 0.5687
90 A 1460.4522 0.0645
91 A 1477.2171 13.8377
92 A 1477.3107 3.8944
93 A 1487.4797 5.8828
94 A 1488.1368 5.1630
95 A 1490.3188 18.4583
96 A 1491.1977 5.1632
97 A 1495.7184 2.3651
98 A 1496.6165 2.3997
99 A 1505.1746 28.0872
100 A 1505.3747 20.7873
101 A 1515.5616 61.2259
102 A 1515.9955 0.5622
103 A 1601.5894 6.1520
104 A 1601.8841 2.3042
105 A 1635.6192 0.0398
106 A 1640.2174 17.3452
107 A 1679.2812 0.1372
108 A 1683.5788 107.8522
109 A 3018.7618 47.7247
110 A 3020.0754 44.6726
111 A 3025.3464 17.1549
112 A 3025.4869 34.3688
113 A 3029.8271 14.7474
114 A 3029.9596 18.8114
115 A 3054.2638 1.7282
116 A 3055.9071 37.9102
117 A 3067.5403 17.4562
118 A 3068.9271 19.3684
119 A 3073.1712 17.6404
120 A 3073.2766 8.0710
121 A 3079.6690 15.8801
122 A 3079.7364 16.8618
123 A 3096.4303 14.8721
124 A 3096.8107 15.7453
125 A 3102.0314 24.0002
126 A 3102.2901 7.4504
127 A 3103.5569 35.5053
128 A 3103.6891 9.4179
129 A 3146.4442 25.8647
130 A 3146.5032 24.1453
131 A 3148.3969 37.5819
132 A 3148.6542 9.7608
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

When I told the people of Northern Ireland that I was an atheist, a woman in the audience stood up and said, "Yes, but is it the God of the Catholics or the God of the Protestants in whom you don't believe?" -- Quentin Crisp