WebMO Job Summary
124553: Bromobenzene radical, Optimize + Vib Freq - Gaussian
Raw Output
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Calculated Quantities
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Overview
Quantity
Value
Route
#N M062X/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Stoichiometry
C
6
H
4
Br(2)
Symmetry
C2V
Basis
6-311+G(2d,p)
UM062X Energy
-2805.08930891 Hartree
ZPE
0.078096 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-2805.005601 Hartree
Enthalpy
-2805.004656 Hartree
Free Energy
-2805.041956 Hartree
C
v
20.747 cal/mol-K
Entropy
78.504 cal/mol-K
Dipole Moment
1.0482 Debye
Server
batch (126992)
CPU time
3218.8 sec
Geometry Sequence Energies
Step
Energy
0
-2805.07552560
1
-2805.08910984
2
-2805.08929743
3
-2805.08930891
4
-2805.08930891
5
-2805.08930891
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
5.65239
0.18854343561
b
1.04052
0.03470801123
c
0.87876
0.02931227843
Partial Charges
Atom
Symbol
Charge
1
C
-0.401814
2
C
0.614292
3
C
-0.401814
4
C
-0.262953
5
C
0.213570
6
C
-0.262953
7
H
0.140697
8
H
0.140697
9
H
0.156501
10
Br
-0.092725
11
H
0.156501
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
B1
186.3177
0.0029
2
B2
260.6970
0.0369
3
A1
328.0950
1.0567
4
A2
409.0689
0.0000
5
B1
467.4744
20.2108
6
B2
612.1008
0.1095
7
A1
681.7720
24.0621
8
B1
694.8699
0.1301
9
B1
806.3172
60.2076
10
A2
829.4249
0.0000
11
B1
965.7447
0.5037
12
A2
982.7480
0.0000
13
A1
995.0670
14.5840
14
A1
1065.1220
11.8143
15
A1
1098.0564
23.6634
16
B2
1109.8093
3.9495
17
A1
1186.9385
0.4701
18
B2
1299.3749
0.0983
19
B2
1317.0893
1.1144
20
B2
1404.8980
7.0366
21
A1
1496.6570
24.6474
22
A1
1601.9144
21.7404
23
B2
1661.3409
0.1032
24
B2
3194.7208
0.2151
25
A1
3194.8029
0.0059
26
B2
3214.4498
0.0041
27
A1
3215.4040
0.1597
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
TO DRY ONE'S EYES AND LAUGH AT A FALL AND BAFFLED, GET UP AND BEGIN AGAIN. R. BROWNING