WebMO Job Summary
124554: Chlorobenzene radical, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N M062X/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Stoichiometry
C
6
H
4
Cl(2)
Symmetry
C2V
Basis
6-311+G(2d,p)
UM062X Energy
-691.12264886 Hartree
ZPE
0.078669 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-691.038583 Hartree
Enthalpy
-691.037638 Hartree
Free Energy
-691.073634 Hartree
C
v
20.296 cal/mol-K
Entropy
75.759 cal/mol-K
Dipole Moment
0.9830 Debye
Server
batch (126993)
CPU time
2606.5 sec
Geometry Sequence Energies
Step
Energy
0
-691.108715534
1
-691.122439927
2
-691.122634762
3
-691.122648860
4
-691.122648860
5
-691.122648860
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
5.65257
0.18854943976
b
1.65882
0.05533227924
c
1.28247
0.04277859452
Partial Charges
Atom
Symbol
Charge
1
C
-0.500130
2
C
0.959325
3
C
-0.500130
4
C
-0.383198
5
C
0.259095
6
C
-0.383198
7
H
0.140903
8
H
0.140903
9
H
0.159841
10
Cl
-0.053252
11
H
0.159841
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
B1
204.0414
0.1170
2
B2
300.2405
0.2816
3
A2
412.3003
0.0000
4
A1
426.6033
1.7156
5
B1
476.4308
19.7237
6
B2
611.6617
0.1253
7
B1
710.7047
0.6051
8
A1
712.3609
27.8336
9
B1
812.6893
63.3901
10
A2
829.6655
0.0000
11
B1
968.6143
1.2639
12
A2
982.0337
0.0000
13
A1
1001.5671
8.9934
14
A1
1063.9475
8.3809
15
B2
1108.3190
4.7576
16
A1
1120.0080
43.8710
17
A1
1181.5050
0.3251
18
B2
1297.9792
0.0448
19
B2
1315.3421
0.5856
20
B2
1406.8555
5.1552
21
A1
1497.8683
29.5398
22
A1
1609.3002
23.6762
23
B2
1661.4321
0.0114
24
B2
3195.0622
0.2256
25
A1
3195.1465
0.0269
26
B2
3214.5909
0.0071
27
A1
3215.5134
0.0109
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
HOW IS IT THAT THE SKY FEEDS THE STARS? -- LUCRETIUS