WebMO Job Summary

124557: 8. 2-chloro-2-methylbutane, NMR - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N MP2/6-311+G(2d,p) NMR Geom=Connectivity
Stoichiometry C5H11Cl
Symmetry C1
Basis 6-311+G(2d,p)
RHF Energy -655.321698178 Hartree
MP2 Energy -656.4474475268 Hartree
Dipole Moment 2.4776 Debye
Server batch (126996)
CPU time 16675.6 sec

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.0566766 0.10195975644
b 2.3970747 0.07995780534
c 1.9326791 0.06446723553

Partial Charges

Atom Symbol Charge
1 C -0.745838  
2 C 1.418828  
3 C -0.225976  
4 C -0.622852  
5 H 0.121797  
6 H 0.148080  
7 H 0.114120  
8 H 0.111050  
9 H 0.112875  
10 C -0.733484  
11 H 0.132909  
12 H 0.132554  
13 H 0.130124  
14 Cl -0.504259  
15 H 0.138064  
16 H 0.132989  
17 H 0.139018  

Absolute NMR Shifts

Atom Symbol Isotropic Anisotropy
1 C* 38.0084 53.0984
2 C* 72.9938 61.7500
3 C* 42.4219 37.8376
4 C* 10.7373 17.0610
5 H* 1.0024 12.1873
6 H* 1.4367 7.2657
7 H* 0.9529 9.0339
8 H* 1.4914 8.1360
9 H* 1.8094 7.2330
10 C* 31.8719 43.4291
11 H* 1.8214 7.3164
12 H* 1.5573 8.4322
13 H* 0.8870 10.8340
14 Cl 750.4555 471.0999
15 H* 1.6753 8.5147
16 H* 1.2205 10.0450
17 H* 1.7544 8.7971
*Denotes shift relative to TMS
TMS shielding (C)
TMS shielding (H)
1H NMR Spectrum
13C NMR Spectrum
Peak Width (ppm)

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