WebMO Job Summary

124564: trans-3-(1,3-Benzodioxol-5-yl)-1-phenyl-2-propen-1-one, NMR - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N M062X/6-311+G(2d,p) NMR Geom=Connectivity
Stoichiometry C16H12O3
Symmetry C1
Basis 6-311+G(2d,p)
RM062X Energy -842.47452832 Hartree
Dipole Moment 3.2735 Debye
Server batch (127003)
CPU time 8179.7 sec

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1.4880379 0.04963560157
b 0.1230082 0.00410311189
c 0.1144571 0.00381787790

Partial Charges

Atom Symbol Charge
1 C 0.078738  
2 O -0.357275  
3 C 0.261980  
4 C 0.435377  
5 C -0.724465  
6 C -0.303605  
7 C 0.647905  
8 C -0.341805  
9 H 0.147676  
10 C -0.134347  
11 C 0.061517  
12 C -0.246558  
13 C 0.896454  
14 C 0.382152  
15 C -0.279242  
16 C -0.058338  
17 C -0.496467  
18 C -0.724089  
19 H 0.135569  
20 H 0.125920  
21 H 0.128299  
22 H 0.128287  
23 H 0.157353  
24 O -0.434800  
25 H 0.117231  
26 H 0.169353  
27 H 0.130064  
28 H 0.138707  
29 O -0.353396  
30 H 0.153228  
31 H 0.158575  

Absolute NMR Shifts

Atom Symbol Isotropic Anisotropy
1 C* 105.2698 47.8973
2 O 197.1302 143.9812
3 C* 166.8180 121.0421
4 C* 168.8866 125.5255
5 C* 126.5743 170.6750
6 C* 136.9523 194.2090
7 C* 148.7371 206.7221
8 C* 131.0111 157.0559
9 H* 7.5953 6.8342
10 C* 168.4634 195.8914
11 C* 135.6598 157.4798
12 C* 207.4432 181.0740
13 C* 160.8775 204.3969
14 C* 150.4356 226.6062
15 C* 149.3909 215.2629
16 C* 154.2451 215.9482
17 C* 147.1196 212.0209
18 C* 148.1621 208.4890
19 H* 8.8815 8.8856
20 H* 8.3607 7.0004
21 H* 8.2585 6.3278
22 H* 8.3247 6.4862
23 H* 9.0791 8.0380
24 O -327.0085 1099.3454
25 H* 8.5669 12.8697
26 H* 8.8909 9.3814
27 H* 8.4199 8.4578
28 H* 7.5407 5.6363
29 O 189.0908 146.4801
30 H* 6.0169 7.9685
31 H* 6.5353 6.4850
*Denotes shift relative to TMS
TMS shielding (C)
TMS shielding (H)
1H NMR Spectrum
13C NMR Spectrum
Peak Width (ppm)

Quote

SEEN ON A WALL AT THE UNIVERSITY OF ILLINOIS AT CHICAGO CIRCLE: TO DO IS TO BE -- SOCRATES TO BE IS TO DO -- SARTRE OO BE DO BE DO -- SINATRA