WebMO Job Summary

124606: 1. p-toluic acid, NMR - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) NMR Geom=Connectivity
Stoichiometry C8H8O2
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -460.288546913 Hartree
Dipole Moment 2.6429 Debye
Server batch (127045)
CPU time 1295.1 sec

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.8202461 0.12742969338
b 0.7866596 0.02624013977
c 0.6549867 0.02184800460

Partial Charges

Atom Symbol Charge
1 C -0.510823  
2 C 0.652762  
3 C -0.330027  
4 C -0.381952  
5 C 0.221350  
6 C -0.276772  
7 C -0.337365  
8 H 0.084572  
9 H 0.113232  
10 C 0.791716  
11 O -0.429267  
12 H 0.307448  
13 O -0.511995  
14 H 0.123821  
15 H 0.086190  
16 H 0.124819  
17 H 0.145792  
18 H 0.126497  

Absolute NMR Shifts

Atom Symbol Isotropic Anisotropy
1 C* 23.4074 40.0957
2 C* 151.4696 207.9902
3 C* 134.8372 166.9171
4 C* 137.9028 193.8351
5 C* 131.7062 161.7064
6 C* 136.1026 186.7316
7 C* 133.6508 164.1948
8 H* 7.4869 7.3171
9 H* 8.3185 8.0860
10 C* 172.0206 84.5777
11 O 127.1628 188.1738
12 H* 5.6607 9.8673
13 O -66.4718 518.7221
14 H* 8.5096 7.5078
15 H* 7.5589 7.4061
16 H* 2.3101 7.2888
17 H* 2.6462 7.9628
18 H* 2.3648 7.3536
*Denotes shift relative to TMS
TMS shielding (C)
TMS shielding (H)
1H NMR Spectrum
13C NMR Spectrum
Peak Width (ppm)

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