WebMO Job Summary

125032: Triplet Methylene, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Stoichiometry CH2(3)
Symmetry C2V
Basis 6-311+G(2d,p)
UB3LYP Energy -39.1666997813 Hartree
ZPE 0.017152 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -39.146686 Hartree
Enthalpy -39.145741 Hartree
Free Energy -39.167903 Hartree
Cv 6.279 cal/mol-K
Entropy 46.642 cal/mol-K
Dipole Moment 0.6581 Debye
Server batch (127471)
CPU time 39.9 sec

Geometry Sequence Energies

Step Energy  
0 -39.1485311670  
1 -39.1628344159  
2 -39.1666691356  
3 -39.1666997813  
4 -39.1666997813  
5 -39.1666997813  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1713.89307 57.16931911609
b 252.15661 8.41103914629
c 219.81615 7.33227751847

Partial Charges

Atom Symbol Charge
1 C -0.268160  
2 H 0.134080  
3 H 0.134080  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A1 1058.2145 10.9637
2 A1 3115.9308 0.6312
3 B2 3354.7873 0.7552
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

FRICTION IS A DRAG, AND ENTROPY AIN'T WHAT IT USED TO BE.