WebMO Job Summary

200421: Benzoic acid, NMR - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) NMR Geom=Connectivity
Stoichiometry C7H6O2
Symmetry CS
Basis 6-311+G(2d,p)
RB3LYP Energy -420.958902304 Hartree
Dipole Moment 2.1331 Debye
Server batch (202810)
CPU time 791.6 sec

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.8932199 0.12986383734
b 1.2277099 0.04095199420
c 0.9333744 0.03113401872

Partial Charges

Atom Symbol Charge
1 C -0.135038  
2 C -0.056508  
3 C -0.130432  
4 C -0.249165  
5 C 0.510996  
6 C -0.350155  
7 H 0.125554  
8 C 0.530340  
9 O -0.507767  
10 O -0.436772  
11 H 0.310097  
12 H 0.115794  
13 H 0.090219  
14 H 0.091387  
15 H 0.091450  

Absolute NMR Shifts

Atom Symbol Isotropic Anisotropy
1 C* 133.3442 185.5544
2 C* 138.6779 193.6297
3 C* 132.8045 184.6238
4 C* 136.0068 189.6064
5 C* 134.5044 164.8003
6 C* 137.5947 197.5639
7 H* 8.6528 7.5770
8 C* 172.2492 84.1804
9 O -69.5631 525.0212
10 O 126.8261 187.5342
11 H* 5.7638 9.7903
12 H* 8.4431 8.1284
13 H* 7.6822 5.4552
14 H* 7.8538 5.5108
15 H* 7.6874 5.4348
*Denotes shift relative to TMS
TMS shielding (C)
TMS shielding (H)
1H NMR Spectrum
13C NMR Spectrum
Peak Width (ppm)

Quote

There are more things in heaven and earth, Horatio, than are dreamt of in your philosophy. -- Hamlet, Act I, Scene 5