WebMO Job Summary
263300: axial 4-tBu-cyclohexanone, Optimize + Vib Freq - Gaussian
Raw Output
Save Notes
Calculated Quantities
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Overview
Quantity
Value
Route
#N M062X/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Stoichiometry
C
10
H
18
O
Symmetry
C1
Basis
6-311+G(2d,p)
RM062X Energy
-467.056053642 Hartree
ZPE
0.265637 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-466.779129 Hartree
Enthalpy
-466.778185 Hartree
Free Energy
-466.826448 Hartree
C
v
45.673 cal/mol-K
Entropy
101.578 cal/mol-K
Dipole Moment
3.5916 Debye
Server
batch (270842)
CPU time
56216 sec
Geometry Sequence Energies
Step
Energy
0
-467.048935602
1
-467.055504249
2
-467.054193497
3
-467.055856743
4
-467.055831830
5
-467.055947970
6
-467.056018577
7
-467.056038750
8
-467.056046445
9
-467.056049914
10
-467.056053258
11
-467.056053376
12
-467.056053642
13
-467.056053642
14
-467.056053642
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.02907
0.06768248986
b
0.73722
0.02459101223
c
0.67389
0.02247855081
Partial Charges
Atom
Symbol
Charge
1
C
-0.447578
2
C
-0.294609
3
C
0.332507
4
C
-0.299988
5
C
-0.446332
6
C
-0.030859
7
H
0.144558
8
C
0.127163
9
C
-0.464654
10
H
0.161520
11
H
0.159267
12
H
0.154383
13
C
-0.540774
14
H
0.164277
15
H
0.166092
16
H
0.164508
17
C
-0.486847
18
H
0.151003
19
H
0.171007
20
H
0.161016
21
H
0.175086
22
H
0.163030
23
H
0.166686
24
H
0.176270
25
O
-0.411599
26
H
0.167893
27
H
0.175191
28
H
0.177008
29
H
0.164775
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
60.7918
4.3064
2
A
84.7621
0.7975
3
A
167.9203
1.2802
4
A
203.2027
1.1958
5
A
233.9831
0.1127
6
A
284.1932
0.1340
7
A
296.9081
0.2495
8
A
324.3710
0.0542
9
A
349.3564
0.6975
10
A
359.4787
0.1920
11
A
378.4341
0.5005
12
A
392.1542
0.1272
13
A
407.5084
0.7535
14
A
433.6733
2.3336
15
A
462.2648
0.8416
16
A
494.2185
0.9298
17
A
512.1060
8.1061
18
A
620.0357
0.2581
19
A
664.9116
2.1390
20
A
747.4080
0.9673
21
A
764.0838
1.8206
22
A
790.0303
12.3817
23
A
842.4959
1.0931
24
A
902.6766
3.1408
25
A
929.9688
3.6544
26
A
947.7525
0.7717
27
A
950.4817
0.8217
28
A
957.5335
1.7099
29
A
964.7511
0.4912
30
A
993.5903
3.4333
31
A
1027.9314
0.5240
32
A
1048.8923
0.2206
33
A
1065.5989
1.8159
34
A
1098.7778
8.2869
35
A
1113.9042
2.5307
36
A
1154.0986
4.6856
37
A
1158.1166
9.3861
38
A
1206.3502
4.5282
39
A
1243.9842
7.7994
40
A
1251.0309
6.2018
41
A
1263.7623
6.4998
42
A
1267.6823
10.5187
43
A
1312.5532
0.7241
44
A
1345.9041
0.7241
45
A
1350.3530
5.5542
46
A
1359.2022
11.7435
47
A
1379.9027
8.0325
48
A
1386.0180
2.5071
49
A
1399.7780
10.0586
50
A
1404.5944
7.1361
51
A
1408.7322
3.6012
52
A
1437.9693
13.7317
53
A
1470.1030
10.0441
54
A
1477.8862
8.2413
55
A
1487.4995
3.6621
56
A
1489.8846
0.7101
57
A
1492.5702
1.9056
58
A
1502.2401
7.7502
59
A
1509.0247
15.2027
60
A
1520.3659
13.9335
61
A
1522.1586
9.4385
62
A
1531.0852
8.2335
63
A
1839.2343
280.7076
64
A
3019.4073
11.0080
65
A
3034.2745
18.3545
66
A
3041.1972
11.4440
67
A
3042.5540
22.2165
68
A
3048.1747
7.2605
69
A
3055.7166
30.2626
70
A
3061.3829
18.9911
71
A
3080.4005
8.7180
72
A
3091.1098
19.7058
73
A
3107.3049
15.7945
74
A
3108.4018
5.9189
75
A
3109.2843
6.5075
76
A
3114.4565
67.8157
77
A
3120.6028
11.1806
78
A
3122.1891
11.1427
79
A
3122.9308
32.5451
80
A
3132.4332
5.4900
81
A
3141.2250
17.7128
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
My opinions may have changed, but not the fact that I am right. -- Ashleigh Brilliant