WebMO Job Summary

350788: Pentane conj. base, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N MP2/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry C5H11(1-)
Symmetry CS
Basis 6-31G(d)
RHF Energy -195.711497914 Hartree
MP2 Energy -196.37669976163 Hartree
ZPE 0.147752 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -196.222057 Hartree
Enthalpy -196.221112 Hartree
Free Energy -196.258982 Hartree
Cv 23.693 cal/mol-K
Entropy 79.703 cal/mol-K
Dipole Moment 2.0404 Debye
Server batch (360124)
CPU time 370.6 sec

Geometry Sequence Energies

Step Energy  
0 -195.701499188  
1 -195.711342169  
2 -195.711507275  
3 -195.711498291  
4 -195.711490989  
5 -195.711497914  
6 -195.711497914  
7 -195.711497914  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 18.44660 0.61531234385
b 1.97253 0.06579651847
c 1.87488 0.06253926508

Partial Charges

Atom Symbol Charge
1 C -0.456766  
2 C -0.246562  
3 C -0.502438  
4 C -0.246562  
5 C -0.456766  
6 H 0.118883  
7 H 0.123928  
8 H 0.122446  
9 H 0.074213  
10 H 0.035749  
11 H -0.041344  
12 H 0.074213  
13 H 0.035749  
14 H 0.118883  
15 H 0.122446  
16 H 0.123928  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 110.4355 1.0062
2 A' 124.3159 20.7882
3 A' 182.5623 10.8857
4 A' 266.1070 7.0183
5 A" 270.7850 0.3980
6 A' 411.2591 0.4337
7 A" 414.7940 18.5064
8 A" 802.9064 0.2090
9 A' 813.7574 66.1820
10 A' 835.4190 58.3866
11 A' 907.0368 10.1895
12 A" 942.6399 2.0339
13 A" 1029.0497 13.7278
14 A' 1064.3319 24.8442
15 A" 1078.9957 1.3711
16 A" 1131.3192 20.7677
17 A' 1151.7243 15.9343
18 A' 1231.1415 2.9397
19 A" 1297.0810 0.3088
20 A' 1305.5431 0.6829
21 A" 1317.5107 110.8199
22 A' 1386.4571 2.4516
23 A" 1403.1533 30.7028
24 A" 1434.9073 4.6571
25 A' 1438.3180 0.6129
26 A" 1540.0600 3.7903
27 A' 1540.0679 6.9207
28 A" 1545.0998 1.0617
29 A' 1548.6744 11.1190
30 A" 1566.4223 0.9554
31 A' 1572.1688 10.4798
32 A" 2773.3189 71.1115
33 A' 2775.6074 931.2194
34 A' 2880.2769 282.8660
35 A" 2996.2049 0.9416
36 A' 2998.7790 331.1647
37 A" 3070.0407 134.1473
38 A' 3071.1330 10.4072
39 A' 3145.2588 148.9615
40 A" 3145.3671 48.1651
41 A' 3167.7606 166.7040
42 A" 3168.0059 3.3822
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THE THINKER DIES, BUT HIS THOUGHTS ARE BEYOND THE REACH OF DESTRUCTION. MEN ARE MORTAL; BUT IDEAS ARE IMMORTAL. -- WALTER LIPPMANN