WebMO Job Summary

350897: BCl3, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N MP2/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry BCl3
Symmetry D3H
Basis 6-31G(d)
RHF Energy -1403.25422138 Hartree
MP2 Energy -1403.7240825435 Hartree
ZPE 0.008053 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -1403.711746 Hartree
Enthalpy -1403.710802 Hartree
Free Energy -1403.743448 Hartree
Cv 12.704 cal/mol-K
Entropy 68.709 cal/mol-K
Dipole Moment 0.0000 Debye
Server batch (360235)
CPU time 51.3 sec

Geometry Sequence Energies

Step Energy  
0 -1403.25106313  
1 -1403.25416857  
2 -1403.25422138  
3 -1403.25422138  
4 -1403.25422138  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.19203 0.10647465988
b 3.19203 0.10647465988
c 1.59601 0.05323716316

Partial Charges

Atom Symbol Charge
1 B 0.269023  
2 Cl -0.089674  
3 Cl -0.089674  
4 Cl -0.089674  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 E' 272.0732 0.9874
2 E' 272.0732 0.9874
3 A2" 478.6309 9.5987
4 A1' 496.1422 0.0000
5 E' 1007.8856 404.8149
6 E' 1007.8856 404.8149
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

CHRISTMAS IS ON TOP OF A STEEP HILL. THE CLOSER YOU GET, THE STEEPER THE HILL IS. -- LINUS, OF PEANUTS