WebMO Job Summary

377254: Ethanol (C2H5OH), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N MP2/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C2H6O
Symmetry CS
Basis 6-31G(d)
RHF Energy -154.074312252 Hartree
MP2 Energy -154.51696938434 Hartree
ZPE 0.082119 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -154.430647 Hartree
Enthalpy -154.429703 Hartree
Free Energy -154.460159 Hartree
Cv 13.130 cal/mol-K
Entropy 64.101 cal/mol-K
Dipole Moment 1.8093 Debye
Server batch (388072)
CPU time 30.5 sec

Geometry Sequence Energies

Step Energy  
0 -154.071825920  
1 -154.074171485  
2 -154.074381074  
3 -154.074312252  
4 -154.074312252  
5 -154.074312252  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 34.75154 1.15918659968
b 9.45217 0.31529045337
c 8.19446 0.27333776355

Partial Charges

Atom Symbol Charge
1 C -0.482957  
2 C 0.005085  
3 O -0.737661  
4 H 0.434594  
5 H 0.138824  
6 H 0.138824  
7 H 0.174885  
8 H 0.153522  
9 H 0.174885  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 264.8441 35.0001
2 A" 315.1510 107.6611
3 A' 425.8590 12.7472
4 A" 846.5278 0.0087
5 A' 936.3704 10.8310
6 A' 1077.9738 50.5164
7 A' 1146.1827 22.0327
8 A" 1222.3526 4.6884
9 A' 1311.5225 84.6480
10 A" 1336.0517 0.1867
11 A' 1454.8972 0.7393
12 A' 1509.4922 16.9601
13 A" 1549.3616 4.9829
14 A' 1566.1632 3.5402
15 A' 1598.2465 2.0154
16 A' 3059.5513 59.9709
17 A" 3101.5525 62.9752
18 A' 3117.4664 11.3782
19 A' 3208.7569 21.2379
20 A" 3219.8204 22.1676
21 A' 3777.9068 21.9946
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

ANYONE WHO IS NOT SHOCKED BY QUANTUM THEORY HAS NOT UNDERSTOOD IT. -- NIELS BOHR(1885-1962)