WebMO Job Summary

378671: Transition State 3 Haber-Bosch, TS Opt + Freq - Gaussian

Calculated Quantities

Expand all

Overview

Quantity Value
Route #N PBE1PBE/6-31G(d) OPT=(TS,NoEigenTest,NewEstmFC) Geom=Connectivity F
Stoichiometry H4N2
Symmetry C1
Basis 6-31G(d)
RPBE1PBE Energy -111.611673101 Hartree
ZPE 0.047453 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -111.560719 Hartree
Enthalpy -111.559775 Hartree
Free Energy -111.587144 Hartree
Cv 9.677 cal/mol-K
Entropy 57.605 cal/mol-K
Dipole Moment 3.8988 Debye
Server batch (389574)
CPU time 75.9 sec

Geometry Sequence Energies

Step Energy  
0 -111.611673032  
1 -111.604350313  
2 -111.616534884  
3 -111.624664261  
4 -111.614500429  
5 -111.608837609  
6 -111.610008569  
7 -111.610735459  
8 -111.611628996  
9 -111.611468063  
10 -111.611335901  
11 -111.611601143  
12 -111.610668869  
13 -111.611602117  
14 -111.611666968  
15 -111.611672935  
16 -111.611673058  
17 -111.611673101  
18 -111.611673101  
19 -111.611673101  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 139.93341 4.66767612946
b 21.69809 0.72377037584
c 20.66727 0.68938592178

Partial Charges

Atom Symbol Charge
1 N -0.752631  
2 N -0.706767  
3 H 0.276487  
4 H 0.426252  
5 H 0.369131  
6 H 0.387528  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A -1408.1584 867.0347
2 A 287.7389 38.6943
3 A 681.9594 17.5274
4 A 904.3511 68.3042
5 A 952.5774 70.5542
6 A 1412.1078 11.1365
7 A 1504.7451 32.7943
8 A 1597.2923 21.7153
9 A 2861.1569 124.6823
10 A 3403.8788 40.9665
11 A 3546.7794 14.7908
12 A 3677.0349 30.8352
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THOSE WITH THE GOLD MAKE THE RULES. -- PETER'S GOLDEN RULE