WebMO Job Summary

378676: HCN Transition State, TS Opt + Freq - Gaussian

Calculated Quantities

Expand all

Overview

Quantity Value
Route #N MP2/6-31G(d) OPT=(TS,NoEigenTest,NewEstmFC) Geom=Connectivity FREQ
Stoichiometry CHN
Symmetry CS
Basis 6-31G(d)
RHF Energy -92.7912602848 Hartree
MP2 Energy -93.067468397495 Hartree
ZPE 0.010997 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -93.053639 Hartree
Enthalpy -93.052695 Hartree
Free Energy -93.077482 Hartree
Cv 5.970 cal/mol-K
Entropy 52.170 cal/mol-K
Dipole Moment 1.3719 Debye
Server batch (389579)
CPU time 15.5 sec

Geometry Sequence Energies

Step Energy  
0 -92.7912603239  
1 -92.7933577275  
2 -92.7909330805  
3 -92.7913014224  
4 -92.7912602848  
5 -92.7912602848  
6 -92.7912602848  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 416.26741 13.88518619771
b 54.07423 1.80372216035
c 47.85742 1.59635170008

Partial Charges

Atom Symbol Charge
1 C -0.022200  
2 N -0.268976  
3 H 0.291176  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A' -1309.9196 159.9005
2 A' 2102.5342 3.0121
3 A' 2724.4098 177.0824
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

NO HUMAN INVESTIGATION CAN BECOME REAL SCIENCE WITHOUT GOING THROUGH MATHEMATICAL PEOPLE. -- LEONARDO DA VINCI, IN "PENSIERI" CA. 1492