WebMO Job Summary

402289: PCl2F3 (eee), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry Cl2F3P
Symmetry D3H
Basis 6-31G(d)
RB3LYP Energy -1561.34407026 Hartree
ZPE 0.013079 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -1561.324372 Hartree
Enthalpy -1561.323428 Hartree
Free Energy -1561.361234 Hartree
Cv 21.642 cal/mol-K
Entropy 79.570 cal/mol-K
Dipole Moment 0.0000 Debye
Server batch (413459)
CPU time 227 sec

Geometry Sequence Energies

Step Energy  
0 -1561.12870844  
1 -1561.18153240  
2 -1561.19678585  
3 -1561.23905003  
4 -1561.30706533  
5 -1561.34178692  
6 -1561.34405468  
7 -1561.34407026  
8 -1561.34407026  
9 -1561.34407026  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.55645 0.11863040264
b 1.33249 0.04444708212
c 1.33249 0.04444708212

Partial Charges

Atom Symbol Charge
1 P 1.261523  
2 F -0.256829  
3 Cl -0.245518  
4 Cl -0.245518  
5 F -0.256829  
6 F -0.256829  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 E' 116.4127 0.0666
2 E' 116.4153 0.0665
3 ?A 348.5194 12.8788
4 ?A 348.5235 12.8774
5 ?A 352.6758 0.0000
6 E" 371.2026 0.0000
7 E" 371.2044 0.0000
8 A2" 451.0315 1.8414
9 A2" 587.6391 683.3474
10 A1' 707.3714 0.0000
11 E' 985.0705 188.8096
12 E' 985.0748 188.8084
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

NEVER TEACH A PIG TO SING. IT WASTES YOUR TIME AND ANNOYS THE PIG. -- SEEN ON A GREETING CARD