WebMO Job Summary

402291: PCl2F3 (aee), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry Cl2F3P
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -1561.3484781 Hartree
ZPE 0.013282 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -1561.328690 Hartree
Enthalpy -1561.327746 Hartree
Free Energy -1561.366979 Hartree
Cv 21.418 cal/mol-K
Entropy 82.573 cal/mol-K
Dipole Moment 0.6298 Debye
Server batch (413461)
CPU time 339.3 sec

Geometry Sequence Energies

Step Energy  
0 -1561.11567688  
1 -1561.16705757  
2 -1561.25226592  
3 -1561.34734236  
4 -1561.34772074  
5 -1561.34820249  
6 -1561.34846660  
7 -1561.34847321  
8 -1561.34847663  
9 -1561.34847784  
10 -1561.34847810  
11 -1561.34847810  
12 -1561.34847810  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.24690 0.07494851655
b 1.85752 0.06196019781
c 1.41472 0.04718997968

Partial Charges

Atom Symbol Charge
1 P 1.174841  
2 Cl -0.106067  
3 Cl -0.235221  
4 F -0.319268  
5 F -0.257142  
6 F -0.257142  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 120.8472 0.0027
2 A' 143.9582 0.4392
3 A' 278.9336 1.1603
4 A" 335.1870 6.4110
5 A' 361.7058 5.8053
6 A' 404.4885 32.2646
7 A" 470.9227 10.3289
8 A' 478.0277 100.0397
9 A' 550.8614 97.0699
10 A' 841.6816 217.7787
11 A' 866.2944 297.0604
12 A" 977.3483 180.5380
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

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