WebMO Job Summary

402294: PF5 (trig bipyr), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry F5P
Symmetry D3H
Basis 6-31G(d)
RB3LYP Energy -840.676371392 Hartree
ZPE 0.016729 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -840.654171 Hartree
Enthalpy -840.653226 Hartree
Free Energy -840.687644 Hartree
Cv 18.608 cal/mol-K
Entropy 72.439 cal/mol-K
Dipole Moment 0.0000 Debye
Server batch (413464)
CPU time 207.4 sec

Geometry Sequence Energies

Step Energy  
0 -840.245932732  
1 -840.313388717  
2 -840.431923777  
3 -840.615065856  
4 -840.673424864  
5 -840.673322384  
6 -840.675802683  
7 -840.676049010  
8 -840.676371392  
9 -840.676371392  
10 -840.676371392  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.59987 0.12007873794
b 3.02511 0.10090680800
c 3.02511 0.10090680800

Partial Charges

Atom Symbol Charge
1 P 1.452289  
2 F -0.268918  
3 F -0.322768  
4 F -0.322768  
5 F -0.268918  
6 F -0.268918  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 E' 173.6598 0.0349
2 E' 173.6615 0.0350
3 E" 477.9325 0.0000
4 E" 477.9351 0.0000
5 E' 503.7486 37.9663
6 E' 503.7514 37.9778
7 A2" 543.3773 47.2382
8 A1' 668.5898 0.0000
9 A1' 783.5257 0.0000
10 A2" 995.9898 363.2105
11 E' 1020.4179 247.6644
12 E' 1020.4386 247.6536
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

You never know when you're making a memory. -- Rickie Lee Jones