WebMO Job Summary

402303: SClF5, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry ClF5S
Symmetry C4V
Basis 6-31G(d)
RB3LYP Energy -1357.4468873 Hartree
ZPE 0.018355 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -1357.422051 Hartree
Enthalpy -1357.421107 Hartree
Free Energy -1357.458237 Hartree
Cv 23.816 cal/mol-K
Entropy 78.147 cal/mol-K
Dipole Moment 0.3159 Debye
Server batch (413473)
CPU time 167.9 sec

Geometry Sequence Energies

Step Energy  
0 -1357.37739937  
1 -1357.40628537  
2 -1357.43996214  
3 -1357.44448829  
4 -1357.44556138  
5 -1357.44685832  
6 -1357.44688338  
7 -1357.44688730  
8 -1357.44688730  
9 -1357.44688730  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.56564 0.08558053852
b 1.73564 0.05789471862
c 1.73564 0.05789471862

Partial Charges

Atom Symbol Charge
1 S 1.483901  
2 F -0.275152  
3 F -0.285402  
4 F -0.285402  
5 Cl -0.067140  
6 F -0.285402  
7 F -0.285402  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 E 240.3397 0.0952
2 E 240.3397 0.0952
3 B2 307.1959 0.0000
4 A1 368.1798 5.6320
5 E 399.7219 1.6064
6 E 399.7219 1.6064
7 B1 456.6339 0.0000
8 E 524.9414 15.3829
9 E 524.9414 15.3829
10 A1 561.0628 94.9213
11 B2 632.9049 0.0000
12 A1 682.2266 2.7650
13 A1 854.4356 388.7989
14 E 932.0985 322.1038
15 E 932.0985 322.1038
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THEREFORE SHALL EVIL COME UPON THEE... THOU SHALT NOT KNOW FROM WHENCE IT RISETH... AND MISCHIEF SHALL FALL UPON THEE... THOU SHALT NOT BE ABLE TO PUT IT OFF... AND DESOLATION SHALL COME UPON THEE SUDDENLY... WHICH THOU SHALT NOT KNOW... ISAIAH 47.11