WebMO Job Summary

456299: PCl5, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry Cl5P
Symmetry D3H
Basis 6-31G(d)
RB3LYP Energy -2642.35683833 Hartree
ZPE 0.008312 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -2642.340365 Hartree
Enthalpy -2642.339420 Hartree
Free Energy -2642.381632 Hartree
Cv 25.551 cal/mol-K
Entropy 88.842 cal/mol-K
Dipole Moment 0.0000 Debye
Server batch (467488)
CPU time 146.7 sec

Geometry Sequence Energies

Step Energy  
0 -2642.34751316  
1 -2642.35534016  
2 -2642.35668271  
3 -2642.35678678  
4 -2642.35683833  
5 -2642.35683833  
6 -2642.35683833  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1.12347 0.03747492540
b 0.90799 0.03028728628
c 0.90799 0.03028728628

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 E' 87.4974 0.7357
2 E' 87.4983 0.7356
3 E" 252.7894 0.0000
4 E" 252.7907 0.0000
5 E' 261.1575 3.4018
6 E' 261.1578 3.4025
7 A1' 266.8479 0.0000
8 A2" 292.9022 5.5564
9 A1' 367.5375 0.0000
10 A2" 423.9430 327.5175
11 E' 547.2081 179.5199
12 E' 547.2185 179.5260
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

SUCCESS-- IF YOU HAVE TRIED TO DO SOMETHING AND FAILED YOU ARE BETTER OFF THAN IF YOU HAD TRIED TO DO NOTHING AND SUCCEEDED. -- FROM THE BACK OF A SUGAR PACKET