WebMO Job Summary
567398: 5. m-nitro bromobenzene arenium [C6H5O2NBr(+1)], Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N M062X/cc-pVTZ OPT FREQ Geom=Connectivity
Stoichiometry
C
6
H
5
BrNO
2
(1+)
Symmetry
C1
Basis
CC-pVTZ
RM062X Energy
-3010.62036913 Hartree
ZPE
0.103756 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-3010.507941 Hartree
Enthalpy
-3010.506997 Hartree
Free Energy
-3010.552456 Hartree
C
v
31.326 cal/mol-K
Entropy
95.676 cal/mol-K
Dipole Moment
5.6956 Debye
Server
chem344 (2213932)
CPU time
56589.6 sec
Geometry Sequence Energies
Step
Energy
0
-3010.47331135
1
-3010.54847781
2
-3010.58952074
3
-3010.60798963
4
-3010.60774902
5
-3010.61172879
6
-3010.59933882
7
-3010.61336052
8
-3010.61614034
9
-3010.61687856
10
-3010.61855254
11
-3010.61969655
12
-3010.62025457
13
-3010.62034732
14
-3010.62036350
15
-3010.62036800
16
-3010.62036907
17
-3010.62036913
18
-3010.62036913
19
-3010.62036913
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.07807
0.06931695393
b
0.48058
0.01603042329
c
0.39498
0.01317511463
Partial Charges
Atom
Symbol
Charge
1
C
-0.073813
2
C
-0.024191
3
C
-0.063930
4
C
0.075301
5
C
-0.062210
6
C
-0.032127
7
H
0.218019
8
H
0.175272
9
H
0.199191
10
Br
0.099548
11
H
0.236348
12
N
0.390766
13
O
-0.201084
14
O
-0.203120
15
H
0.266031
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
42.8908
0.9041
2
A
102.4656
3.5706
3
A
137.1095
4.1530
4
A
176.9144
1.0107
5
A
297.1846
2.9588
6
A
310.0028
0.3050
7
A
351.6575
0.4696
8
A
385.4958
0.9889
9
A
457.0173
10.0218
10
A
512.2238
2.0673
11
A
586.9797
5.9076
12
A
634.9990
12.6638
13
A
693.9010
45.3348
14
A
735.1610
43.5562
15
A
815.0605
18.0047
16
A
872.4516
69.6693
17
A
908.7709
38.1263
18
A
957.0629
50.0874
19
A
1022.5055
12.8610
20
A
1026.5279
29.5713
21
A
1056.1828
4.0864
22
A
1073.1444
4.9758
23
A
1093.0744
20.8524
24
A
1119.1124
102.8498
25
A
1144.5263
17.6115
26
A
1211.3254
3.3470
27
A
1305.8638
8.4999
28
A
1369.5121
18.0409
29
A
1426.3567
106.6267
30
A
1450.7248
205.6973
31
A
1490.0514
159.1799
32
A
1578.6353
77.3890
33
A
1646.9390
50.2507
34
A
1775.2350
334.9011
35
A
2881.7708
100.8867
36
A
3211.3839
0.2722
37
A
3217.9251
29.9369
38
A
3227.4843
32.4121
39
A
3237.8366
30.7756
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
ON A TOMBSTONE, "HERE LIES LESTER MOORE, FOUR SLUGS FROM A 44, NO LES, NO MORE".