WebMO Job Summary

567489: 8. Exo Diels-Alder Product (C9H8O3), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N M062X/cc-pVTZ OPT FREQ Geom=Connectivity
Stoichiometry C9H8O3
Symmetry CS
Basis CC-pVTZ
RM062X Energy -573.422618823 Hartree
ZPE 0.157411 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -573.256941 Hartree
Enthalpy -573.255997 Hartree
Free Energy -573.298911 Hartree
Cv 33.843 cal/mol-K
Entropy 90.319 cal/mol-K
Dipole Moment 4.8789 Debye
Server chem344 (2215322)
CPU time 40207.8 sec

Geometry Sequence Energies

Step Energy  
0 -573.409129537  
1 -573.419654890  
2 -573.421529888  
3 -573.422077347  
4 -573.422210456  
5 -573.422605623  
6 -573.422617799  
7 -573.422618823  
8 -573.422618823  
9 -573.422618823  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1.60139 0.05341662064
b 1.05246 0.03510628676
c 0.73829 0.02462670358

Partial Charges

Atom Symbol Charge
1 C -0.056800  
2 C -0.189588  
3 C -0.189588  
4 C -0.056800  
5 C -0.187701  
6 C -0.187701  
7 C 0.293919  
8 O -0.158919  
9 C 0.293919  
10 O -0.282816  
11 O -0.282816  
12 H 0.197130  
13 H 0.197130  
14 C -0.323140  
15 H 0.163390  
16 H 0.151011  
17 H 0.157899  
18 H 0.151786  
19 H 0.151786  
20 H 0.157899  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 77.5611 0.1001
2 A' 140.3132 5.4962
3 A' 187.4108 3.2051
4 A" 209.1661 1.2127
5 A' 329.4849 6.0245
6 A" 435.4834 1.0997
7 A' 437.3355 9.5971
8 A' 505.9376 1.1181
9 A" 534.6818 0.8995
10 A' 634.8675 0.7082
11 A" 652.2719 17.9038
12 A' 674.0355 22.5556
13 A" 700.7139 1.9172
14 A' 747.4865 23.7697
15 A" 787.7073 14.6788
16 A' 817.7009 0.0547
17 A" 836.9166 0.7055
18 A' 880.2557 21.9688
19 A" 920.0789 11.3414
20 A' 920.5973 2.9173
21 A' 932.9377 3.8693
22 A" 939.1654 4.3236
23 A" 975.8548 13.4856
24 A' 978.8870 1.0509
25 A" 998.8327 157.9686
26 A" 1018.6512 5.6121
27 A' 1028.5127 0.6666
28 A' 1043.9835 8.2406
29 A" 1123.4355 60.5523
30 A' 1123.7635 1.7014
31 A" 1132.7169 139.9387
32 A' 1174.6837 2.9546
33 A" 1187.9552 0.2351
34 A' 1252.0113 8.5450
35 A" 1253.4903 0.0165
36 A" 1280.1799 0.5741
37 A' 1286.1929 206.6308
38 A" 1288.9301 0.1731
39 A' 1315.5663 9.6271
40 A" 1325.4259 8.0048
41 A' 1330.9162 14.1775
42 A" 1362.4373 5.2993
43 A' 1510.0365 6.7835
44 A' 1660.0664 2.3550
45 A" 1904.6171 647.9150
46 A' 1973.1669 161.6952
47 A' 3067.2941 14.4888
48 A' 3140.1354 10.1365
49 A" 3144.3783 1.0730
50 A' 3150.5710 2.5288
51 A" 3156.8184 12.9424
52 A' 3159.6742 0.8646
53 A" 3210.2957 0.7347
54 A' 3234.0267 4.0558
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

TOWERING GENIUS DISDAINS A BEATEN PATH. IT SEEKS REGIONS HITHERTO UNEXPLORED. -- ABRAHAM LINCOLN