WebMO Job Summary
103859: H4B(-1), Natural Bond Orbitals 6.0/NRT - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) SP GFINPUT POP=(FULL,NBO6Read) Geom=Connectivity
Stoichiometry
BH
4
(1-)
Symmetry
TD
Basis
6-31G(d)
RB3LYP Energy
-27.2471165452 Hartree
Dipole Moment
0.0000 Debye
Server
batch (105507)
CPU time
13.6 sec
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
121.9029215
4.06624377122
b
121.9029215
4.06624377122
c
121.9029215
4.06624377122
Partial Charges
Atom
Symbol
Charge
1
B
-0.202469
2
H
-0.199383
3
H
-0.199383
4
H
-0.199383
5
H
-0.199383
Molecular Orbitals
Show all
Orbital
Symmetry
Occupancy
Spin
Energy
Actions
1
A1
2
-
-6.42240 Ha
2
A1
2
-
-0.22577 Ha
3
T2
2
-
-0.03235 Ha
4
T2
2
-
-0.03235 Ha
5
T2
2
-
-0.03235 Ha
6
T2
0
-
0.41600 Ha
7
T2
0
-
0.41600 Ha
8
T2
0
-
0.41600 Ha
9
A1
0
-
0.43495 Ha
10
T2
0
-
0.67635 Ha
11
T2
0
-
0.67635 Ha
12
T2
0
-
0.67635 Ha
13
A1
0
-
0.96260 Ha
14
T2
0
-
1.15625 Ha
15
T2
0
-
1.15625 Ha
16
T2
0
-
1.15625 Ha
17
A1
0
-
1.24915 Ha
18
E
0
-
1.56897 Ha
19
E
0
-
1.56897 Ha
20
T2
0
-
2.07630 Ha
21
T2
0
-
2.07630 Ha
22
T2
0
-
2.07630 Ha
23
A1
0
-
3.78171 Ha
Electron density
Electrostatic potential
Electrophilic (HOMO) frontier density
Nucleophilic (LUMO) frontier density
Radical frontier density
Natural Population Analysis
Atom
Symbol
Charge
1
B
-0.60605
2
H
-0.09849
3
H
-0.09849
4
H
-0.09849
5
H
-0.09849
Natural Atomic Orbitals
Show all
Orbital
Description
Occupancy
Spin
Energy
Actions
1
B1 Cor(1s)
1.999992190
-
-6.422358379 Hartree
2
B1 Val(2s)
0.872799711
-
0.306911191 Hartree
3
B1 Ryd(4s)
0.000000000
-
0.990944703 Hartree
4
B1 Ryd(3s)
0.000000000
-
3.772995806 Hartree
5
B1 Val(2p)
0.909715003
-
0.317959643 Hartree
6
B1 Ryd(3p)
0.000000000
-
0.670074106 Hartree
7
B1 Val(2p)
0.909715003
-
0.317959643 Hartree
8
B1 Ryd(3p)
0.000000000
-
0.670074106 Hartree
9
B1 Val(2p)
0.909715003
-
0.317959643 Hartree
10
B1 Ryd(3p)
0.000000000
-
0.670074106 Hartree
11
B1 Ryd(3d)
0.001371811
-
1.970833829 Hartree
12
B1 Ryd(3d)
0.001371811
-
1.970833829 Hartree
13
B1 Ryd(3d)
0.001371811
-
1.970833829 Hartree
14
B1 Ryd(3d)
0.000000000
-
1.568971674 Hartree
15
B1 Ryd(3d)
0.000000000
-
1.568971674 Hartree
16
H2 Val(1s)
1.098419145
-
0.246150373 Hartree
17
H2 Ryd(2s)
0.000067769
-
1.037043757 Hartree
18
H3 Val(1s)
1.098419145
-
0.246150373 Hartree
19
H3 Ryd(2s)
0.000067769
-
1.037043757 Hartree
20
H4 Val(1s)
1.098419145
-
0.246150373 Hartree
21
H4 Ryd(2s)
0.000067769
-
1.037043757 Hartree
22
H5 Val(1s)
1.098419145
-
0.246150373 Hartree
23
H5 Ryd(2s)
0.000067769
-
1.037043757 Hartree
Natural Hybrid Orbitals
Show all
Orbital
Description
Occupancy
Spin
Energy
Actions
1
CR(1)B1 s(100.00%)
1.999992190
-
-6.422358379 Hartree
2
BD(1)B1(H2) 1s(25.00%)p3.00(74.89%)d0.00(0.11%)
0.901515039
-
0.319965942 Hartree
3
BD(1)H2(B1) 2s(100.00%)
1.098419130
-
0.246098047 Hartree
4
BD(1)B1(H3) 1s(25.00%)p3.00(74.89%)d0.00(0.11%)
0.901515039
-
0.319965942 Hartree
5
BD(1)H3(B1) 3s(100.00%)
1.098419130
-
0.246098047 Hartree
6
BD(1)B1(H4) 1s(25.00%)p3.00(74.89%)d0.00(0.11%)
0.901515039
-
0.319965942 Hartree
7
BD(1)H4(B1) 4s(100.00%)
1.098419130
-
0.246098047 Hartree
8
BD(1)B1(H5) 1s(25.00%)p3.00(74.89%)d0.00(0.11%)
0.901515039
-
0.319965942 Hartree
9
BD(1)H5(B1) 5s(100.00%)
1.098419130
-
0.246098047 Hartree
10
RY(1)B1 s(100.00%)
0.000000000
-
1.855112809 Hartree
11
RY(2)B1 s(100.00%)
0.000000000
-
2.908827700 Hartree
12
RY(3)B1 s(0.00%)p1.00(100.00%)
0.000000000
-
0.670074106 Hartree
13
RY(4)B1 s(0.00%)p1.00(100.00%)
0.000000000
-
0.670074106 Hartree
14
RY(5)B1 s(0.00%)p1.00(100.00%)
0.000000000
-
0.670074106 Hartree
15
RY(6)B1 s(0.00%)p1.00(0.15%)d99.99(99.85%)
0.000000000
-
1.964475946 Hartree
16
RY(7)B1 s(0.00%)p1.00(0.15%)d99.99(99.85%)
0.000000000
-
1.964475946 Hartree
17
RY(8)B1 s(0.00%)p1.00(0.15%)d99.99(99.85%)
0.000000000
-
1.964475946 Hartree
18
RY(9)B1 s(0.00%)p0.00(0.00%)d1.00(100.00%)
0.000000000
-
1.568971674 Hartree
19
RY(10)B1 s(0.00%)p0.00(0.00%)d1.00(100.00%)
0.000000000
-
1.568971674 Hartree
20
RY(1)H2 s(100.00%)
0.000067784
-
1.037096083 Hartree
21
RY(1)H3 s(100.00%)
0.000067784
-
1.037096083 Hartree
22
RY(1)H4 s(100.00%)
0.000067784
-
1.037096083 Hartree
23
RY(1)H5 s(100.00%)
0.000067784
-
1.037096083 Hartree
Natural Bond Orbitals
Show all
Orbital
Description
NHOs
Occupancy
Spin
Energy
Actions
1
CR(1)B1
1
1.999992190
-
-6.422358379 Hartree
2
BD(1)B1-H2
2
,
3
1.999795679
-
-0.080578264 Hartree
3
BD(1)B1-H3
4
,
5
1.999795679
-
-0.080578264 Hartree
4
BD(1)B1-H4
6
,
7
1.999795679
-
-0.080578264 Hartree
5
BD(1)B1-H5
8
,
9
1.999795679
-
-0.080578264 Hartree
6
BD*(1)B1-H2
0.000138490
-
0.646642253 Hartree
7
BD*(1)B1-H3
0.000138490
-
0.646642253 Hartree
8
BD*(1)B1-H4
0.000138490
-
0.646642253 Hartree
9
BD*(1)B1-H5
0.000138490
-
0.646642253 Hartree
10
RY(1)B1
10
0.000000000
-
1.855112809 Hartree
11
RY(2)B1
11
0.000000000
-
2.908827700 Hartree
12
RY(3)B1
12
0.000000000
-
0.670074106 Hartree
13
RY(4)B1
13
0.000000000
-
0.670074106 Hartree
14
RY(5)B1
14
0.000000000
-
0.670074106 Hartree
15
RY(6)B1
15
0.000000000
-
1.964475946 Hartree
16
RY(7)B1
16
0.000000000
-
1.964475946 Hartree
17
RY(8)B1
17
0.000000000
-
1.964475946 Hartree
18
RY(9)B1
18
0.000000000
-
1.568971674 Hartree
19
RY(10)B1
19
0.000000000
-
1.568971674 Hartree
20
RY(1)H2
20
0.000067784
-
1.037096083 Hartree
21
RY(1)H3
21
0.000067784
-
1.037096083 Hartree
22
RY(1)H4
22
0.000067784
-
1.037096083 Hartree
23
RY(1)H5
23
0.000067784
-
1.037096083 Hartree
Quote
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