WebMO Job Summary
105280: C10H11O2Br 1,2-ethanediol protected 4'-bromoacetophenone, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
10
H
11
BrO
2
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-3112.42407761 Hartree
ZPE
0.190241 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-3112.221845 Hartree
Enthalpy
-3112.220901 Hartree
Free Energy
-3112.274763 Hartree
C
v
44.788 cal/mol-K
Entropy
113.362 cal/mol-K
Dipole Moment
2.0669 Debye
Server
class (106036)
CPU time
29175 sec
Geometry Sequence Energies
Step
Energy (au)
0
-3112.39993586
1
-3112.41941419
2
-3112.42108352
3
-3112.42235074
4
-3112.42265064
5
-3112.42339279
6
-3112.42358497
7
-3112.42369671
8
-3112.42374720
9
-3112.42384344
10
-3112.42393820
11
-3112.42394809
12
-3112.42396248
13
-3112.42402916
14
-3112.42405834
15
-3112.42406762
16
-3112.42407258
17
-3112.42407653
18
-3112.42407699
19
-3112.42407750
20
-3112.42407745
21
-3112.42407755
22
-3112.42407761
23
-3112.42407761
24
-3112.42407761
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.75935
0.05868559909
b
0.23714
0.00791013895
c
0.23534
0.00785009742
Partial Charges
Atom
Symbol
Charge
1
C
0.278814
2
C
0.810179
3
C
-0.319147
4
C
-0.578482
5
C
0.561242
6
C
-0.548035
7
C
-0.318995
8
H
0.118244
9
H
0.114055
10
Br
-0.056652
11
H
0.114222
12
H
0.115498
13
C
-0.398997
14
H
0.137992
15
H
0.139101
16
H
0.140426
17
O
-0.359987
18
C
0.008378
19
C
-0.006108
20
O
-0.398420
21
H
0.111326
22
H
0.110880
23
H
0.112664
24
H
0.111800
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
19.1047
2.7082
2
A
43.5069
0.4963
3
A
62.1498
0.3474
4
A
131.1486
1.3392
5
A
154.1729
0.5655
6
A
204.8139
1.2629
7
A
223.2475
0.2213
8
A
240.7456
3.0694
9
A
277.4062
0.1527
10
A
326.7388
3.2493
11
A
355.3704
0.8684
12
A
420.2283
0.5709
13
A
424.1210
20.9978
14
A
483.7425
3.7075
15
A
514.6059
9.5030
16
A
604.1595
13.3908
17
A
644.1982
0.7043
18
A
699.3843
2.6480
19
A
708.2997
3.9360
20
A
743.9450
3.1992
21
A
779.1544
5.6234
22
A
847.2274
8.8579
23
A
849.0001
30.9809
24
A
869.2851
3.3431
25
A
877.5884
38.6464
26
A
897.6036
30.0992
27
A
953.1888
21.8616
28
A
979.3143
0.5029
29
A
990.1331
0.0226
30
A
1029.9159
71.5275
31
A
1046.1186
59.0707
32
A
1054.7175
79.4351
33
A
1082.5372
14.0979
34
A
1102.6984
43.0255
35
A
1117.8386
20.4327
36
A
1142.1188
5.9255
37
A
1162.8658
9.0822
38
A
1201.5826
6.3697
39
A
1212.5838
157.5043
40
A
1231.3384
6.4458
41
A
1249.8623
57.6135
42
A
1258.2418
26.1937
43
A
1308.2605
0.0653
44
A
1328.9848
0.0554
45
A
1375.2533
0.2587
46
A
1378.4507
1.1164
47
A
1409.3395
16.9590
48
A
1422.1353
13.7165
49
A
1483.2847
0.2676
50
A
1484.5270
6.2198
51
A
1516.9220
3.1609
52
A
1519.6036
42.2776
53
A
1532.6072
0.9775
54
A
1606.9385
0.9543
55
A
1625.8175
19.7086
56
A
3019.0277
29.6833
57
A
3035.7307
66.2807
58
A
3047.8036
9.0042
59
A
3072.9312
27.3554
60
A
3111.0322
37.4720
61
A
3121.5417
8.7578
62
A
3125.7897
20.9833
63
A
3180.0027
1.0910
64
A
3185.4474
0.3151
65
A
3198.4281
2.8382
66
A
3200.4174
0.6319
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
THE WISE MAN HAS THE POWER TO REASON AWAY WHAT A FOOL BELIEVES. - DOOBIE BROTHERS