WebMO Job Summary
105284: C3H4O cyclopropanone C2v, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
3
H
4
O
Symmetry
C2V
Basis
6-311+G(2d,p)
RB3LYP Energy
-191.944390103 Hartree
ZPE
0.060534 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-191.879836 Hartree
Enthalpy
-191.878891 Hartree
Free Energy
-191.909072 Hartree
C
v
13.598 cal/mol-K
Entropy
63.520 cal/mol-K
Dipole Moment
3.0493 Debye
Server
class (106040)
CPU time
113.8 sec
Geometry Sequence Energies
Step
Energy (au)
0
-191.939246000
1
-191.944048536
2
-191.944352700
3
-191.944389429
4
-191.944390103
5
-191.944390103
6
-191.944390103
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
20.25192
0.67553133708
b
7.48218
0.24957866018
c
5.89210
0.19653930053
Partial Charges
Atom
Symbol
Charge
1
C
-0.111788
2
C
-0.111788
3
H
0.110144
4
H
0.110144
5
C
0.161990
6
O
-0.378990
7
H
0.110144
8
H
0.110144
Vibrational Modes
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Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
B1
306.4732
4.6138
2
B2
503.4126
1.2039
3
A2
645.7282
0.0000
4
B1
702.7357
0.9444
5
A1
710.0365
3.0290
6
B2
950.6834
100.6585
7
A1
1007.2857
19.5220
8
A1
1048.1758
5.6079
9
B2
1062.1351
12.8684
10
B1
1106.3961
0.1157
11
A2
1161.1636
0.0000
12
B2
1418.2572
6.2887
13
A1
1435.0607
3.9199
14
A1
1912.3490
362.9282
15
B2
3108.4960
2.5389
16
A1
3108.6081
0.9343
17
A2
3185.5468
0.0000
18
B1
3198.6179
1.8037
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
HOW IS IT THAT THE SKY FEEDS THE STARS? -- LUCRETIUS