WebMO Job Summary

110074: CH3(+1), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry CH3(1+)
Symmetry D3H
Basis 6-31G(d)
RB3LYP Energy -39.4803876134 Hartree
ZPE 0.031605 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -39.445930 Hartree
Enthalpy -39.444986 Hartree
Free Energy -39.466183 Hartree
Cv 6.253 cal/mol-K
Entropy 44.613 cal/mol-K
Dipole Moment 0.0000 Debye
Server batch (112139)
CPU time 54.5 sec

Geometry Sequence Energies

Step Energy  
0 -39.4803465406  
1 -39.4803876134  
2 -39.4803876134  
3 -39.4803876134  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 278.90594 9.30330075215
b 278.90594 9.30330075215
c 139.45297 4.65165037607

Partial Charges

Atom Symbol Charge
1 C -0.061322  
2 H 0.353774  
3 H 0.353774  
4 H 0.353774  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A2" 1422.6275 12.8310
2 E' 1426.1338 17.8781
3 E' 1426.1346 17.8765
4 A1' 3069.3018 0.0000
5 E' 3264.3443 76.7187
6 E' 3264.3445 76.7173
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

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