WebMO Job Summary

110075: H4N(+1) opt, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry H4N(1+)
Symmetry TD
Basis 6-31G(d)
RB3LYP Energy -56.8938947153 Hartree
ZPE 0.049867 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -56.841179 Hartree
Enthalpy -56.840235 Hartree
Free Energy -56.861345 Hartree
Cv 6.230 cal/mol-K
Entropy 44.431 cal/mol-K
Dipole Moment 0.0000 Debye
Server batch (112140)
CPU time 58.8 sec

Geometry Sequence Energies

Step Energy  
0 -56.8892247212  
1 -56.8938947153  
2 -56.8938947153  
3 -56.8938947153  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 177.44316 5.91886671145
b 177.44316 5.91886671145
c 177.44316 5.91886671145

Partial Charges

Atom Symbol Charge
1 N -0.843665  
2 H 0.460916  
3 H 0.460916  
4 H 0.460916  
5 H 0.460916  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 T2 1522.1656 188.2560
2 T2 1522.1656 188.2560
3 T2 1522.1656 188.2560
4 E 1753.1599 0.0000
5 E 1753.1599 0.0000
6 A1 3363.3454 0.0000
7 T2 3484.2537 198.8369
8 T2 3484.2537 198.8369
9 T2 3484.2537 198.8369
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

DIATOMIC MOLECULES ARE PECULIAR BECAUSE THEY ONLY HAVE TWO ENDS, AND THESE ENDS ARE VERY CLOSE TOGETHER. KLAUS RUEDENBERG, REV.MOD.PHYS. PG 176, 32, (1960)