WebMO Job Summary

110139: O3S opt, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry O3S
Symmetry C2V
Basis 6-31G(d)
RB3LYP Energy -623.759208561 Hartree
ZPE 0.011794 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -623.743819 Hartree
Enthalpy -623.742875 Hartree
Free Energy -623.773235 Hartree
Cv 10.424 cal/mol-K
Entropy 63.898 cal/mol-K
Dipole Moment 0.0011 Debye
Server batch (112204)
CPU time 103.5 sec

Geometry Sequence Energies

Step Energy  
0 -623.652007558  
1 -623.707167780  
2 -623.759089711  
3 -623.759207162  
4 -623.759208561  
5 -623.759208561  
6 -623.759208561  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 9.97456 0.33271550814
b 9.97348 0.33267948322
c 4.98701 0.16634874784

Partial Charges

Atom Symbol Charge
1 S 1.187061  
2 O -0.395574  
3 O -0.395743  
4 O -0.395743  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 B1 454.7422 32.6912
2 B2 497.3648 26.2616
3 A1 498.2226 26.2158
4 A1 1023.0715 0.0005
5 B2 1351.2226 168.5145
6 A1 1352.2478 168.5278
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

IF AT FIRST YOU DON'T SUCCEED, TRY, TRY AGAIN. THEN GIVE UP; THERE'S NO USE BEING A DAMN FOOL ABOUT IT. -- W. C. FIELDS