WebMO Job Summary

110147: O3S(-2), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry O3S(2-)
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -623.648220875 Hartree
ZPE 0.009717 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -623.634795 Hartree
Enthalpy -623.633851 Hartree
Free Energy -623.665147 Hartree
Cv 11.188 cal/mol-K
Entropy 65.868 cal/mol-K
Dipole Moment 1.3179 Debye
Server batch (112212)
CPU time 136.2 sec

Geometry Sequence Energies

Step Energy  
0 -623.594453222  
1 -623.627869917  
2 -623.644371621  
3 -623.648153589  
4 -623.648216605  
5 -623.648219690  
6 -623.648220875  
7 -623.648220875  
8 -623.648220875  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 8.79743 0.29345067780
b 8.79443 0.29335060857
c 4.93155 0.16449880137

Partial Charges

Atom Symbol Charge
1 S 0.507948  
2 O -0.835906  
3 O -0.836021  
4 O -0.836021  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 428.4333 5.5452
2 A' 428.4781 5.5557
3 A' 577.9316 24.1781
4 A' 919.6325 88.8320
5 A" 955.3971 306.2530
6 A' 955.5894 306.2024
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

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