WebMO Job Summary
115083: C4H10 eclipsed butane C2v, Transition State Optimization & - Gaussian
Raw Output
Save Notes
Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT=(TS,NoEigenTest,NewEstmFC) Geom=Connectivity FRE
Stoichiometry
C
4
H
10
Symmetry
C2
Basis
6-31G(d)
RB3LYP Energy
-158.452702019 Hartree
ZPE
0.132870 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-158.314892 Hartree
Enthalpy
-158.313948 Hartree
Free Energy
-158.346314 Hartree
C
v
17.397 cal/mol-K
Entropy
68.119 cal/mol-K
Dipole Moment
0.0624 Debye
Server
batch (117203)
CPU time
131.9 sec
Geometry Sequence Energies
Step
Energy
0
-158.451687145
1
-158.455843888
2
-158.456204086
3
-158.452411363
4
-158.452371610
5
-158.452657207
6
-158.452700681
7
-158.452701682
8
-158.452701963
9
-158.452702019
10
-158.452702019
11
-158.452702019
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
17.89192
0.59681021062
b
3.74113
0.12479066435
c
3.72967
0.12440839989
Partial Charges
Atom
Symbol
Charge
1
C
-0.445365
2
C
-0.247550
3
C
-0.247550
4
C
-0.445365
5
H
0.139760
6
H
0.142166
7
H
0.142793
8
H
0.133184
9
H
0.135011
10
H
0.135011
11
H
0.133184
12
H
0.139760
13
H
0.142166
14
H
0.142793
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
-123.7564
0.0139
2
A
253.0127
0.0003
3
B
259.0798
0.0160
4
B
368.7043
0.2112
5
A
384.1148
0.0089
6
A
745.8925
3.2495
7
B
802.4811
1.7359
8
A
838.5151
0.0112
9
B
988.7735
1.7248
10
A
1014.2356
0.4005
11
B
1027.6672
2.4012
12
A
1088.4291
0.0010
13
A
1178.5302
0.0229
14
B
1190.9438
0.3183
15
B
1317.5097
0.1869
16
A
1318.8239
0.0196
17
B
1362.3724
7.4649
18
A
1404.5973
0.2484
19
A
1441.4247
0.7666
20
B
1441.7035
1.5654
21
A
1520.6378
0.2628
22
B
1526.7047
1.4650
23
B
1531.3808
2.7889
24
A
1532.6039
8.3213
25
B
1537.5753
5.0792
26
A
1541.9059
0.1660
27
B
3033.1235
32.1437
28
A
3033.6212
6.6701
29
B
3039.9166
59.0353
30
A
3040.6851
6.9966
31
B
3056.8806
11.0821
32
A
3071.6053
22.8765
33
B
3104.4134
28.8394
34
A
3106.6943
55.4919
35
A
3108.9439
38.7186
36
B
3109.8266
90.8627
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
MANHOOD BEGINS BY TRYING TO SHAVE FACE, AND ENDS BY TRYING TO SAVE FACE.