WebMO Job Summary
122277: C6H5MgBr phenylmagnesium bromide, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
6
H
5
BrMg
Symmetry
C2V
Basis
6-311+G(2d,p)
RB3LYP Energy
-3006.02969535 Hartree
ZPE
0.090278 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-3005.931414 Hartree
Enthalpy
-3005.930470 Hartree
Free Energy
-3005.974433 Hartree
C
v
27.162 cal/mol-K
Entropy
92.529 cal/mol-K
Dipole Moment
2.1942 Debye
Server
class (123046)
CPU time
1097.1 sec
Geometry Sequence Energies
Step
Energy (au)
0
-3006.02057542
1
-3006.02944602
2
-3006.02967744
3
-3006.02969535
4
-3006.02969535
5
-3006.02969535
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
5.76860
0.19241978396
b
0.35065
0.01169642500
c
0.33056
0.01102629473
Partial Charges
Atom
Symbol
Charge
1
C
-0.208480
2
C
-0.060782
3
C
-0.208480
4
C
-0.296466
5
C
0.721416
6
C
-0.296466
7
H
0.072435
8
Mg
0.527716
9
Br
-0.570686
10
H
0.072435
11
H
0.082396
12
H
0.082568
13
H
0.082396
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
B2
41.6987
5.0158
2
B1
50.6313
4.2602
3
B1
163.1429
36.6454
4
B2
181.9630
29.9517
5
A1
183.6543
0.6539
6
A2
392.4743
0.0000
7
B1
439.5239
13.4181
8
A1
471.4193
116.7769
9
B2
635.4785
0.0077
10
A1
676.9544
12.1176
11
B1
713.4287
53.3701
12
B1
731.0601
12.9546
13
A2
866.0020
0.0000
14
B1
917.5088
0.0098
15
A2
977.7171
0.0000
16
B1
999.0848
0.0008
17
A1
1014.1886
6.4746
18
A1
1039.1517
0.7151
19
B2
1084.9107
0.5959
20
A1
1085.4658
9.5904
21
B2
1184.0139
0.0317
22
A1
1218.8103
0.3841
23
B2
1278.3055
4.4031
24
B2
1363.2857
2.0390
25
B2
1454.3310
9.7749
26
A1
1514.1079
0.1998
27
B2
1600.5392
0.0041
28
A1
1611.6503
0.0001
29
A1
3120.0876
1.2080
30
B2
3121.0937
26.9383
31
A1
3154.3764
0.0833
32
B2
3163.2675
34.8095
33
A1
3178.3192
25.2571
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
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