WebMO Job Summary

122279: OSCl2 thionyl chloride, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method B3LYP
Stoichiometry Cl2OS
Symmetry CS
Basis 6-311+G(2d,p)
RB3LYP Energy -1393.90441769 Hartree
ZPE 0.006662 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -1393.892942 Hartree
Enthalpy -1393.891998 Hartree
Free Energy -1393.927194 Hartree
Cv 14.059 cal/mol-K
Entropy 74.078 cal/mol-K
Dipole Moment 1.4427 Debye
Server class (123048)
CPU time 132 sec

Geometry Sequence Energies

Step Energy (au)  
0 -1393.82516642  
1 -1393.88857142  
2 -1393.89361799  
3 -1393.90327500  
4 -1393.90436341  
5 -1393.90441509  
6 -1393.90441769  
7 -1393.90441769  
8 -1393.90441769  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.91284 0.16387470295
b 2.61847 0.08734275764
c 1.83824 0.06131708624

Partial Charges

Atom Symbol Charge
1 S 0.521506  
2 O -0.364247  
3 Cl -0.078629  
4 Cl -0.078629  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A' 173.5156 0.0302
2 A" 270.3584 6.3863
3 A' 326.8177 8.0676
4 A" 435.7630 191.7699
5 A' 477.4814 67.9339
6 A' 1240.3797 178.2063
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

IF YOU WANT TO LEARN FROM THE THEORETICAL PHYSICISTS ABOUT THE METHODS WHICH THEY USE, I ADVISE YOU TO FOLLOW THIS PRINCIPLE VERY STRICTLY: DON'T LISTEN TO THEIR WORDS; PAY ATTENTION, INSTEAD, TO THEIR ACTIONS. -- A.EINSTEIN, 1934