WebMO Job Summary

122939: C8H8O acetophenone, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method B3LYP
Stoichiometry C8H8O
Symmetry CS
Basis 6-311+G(2d,p)
RB3LYP Energy -385.011751256 Hartree
ZPE 0.137210 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -384.866660 Hartree
Enthalpy -384.865716 Hartree
Free Energy -384.907463 Hartree
Cv 29.715 cal/mol-K
Entropy 87.865 cal/mol-K
Dipole Moment 3.2038 Debye
Server class (123723)
CPU time 2647.6 sec

Geometry Sequence Energies

Step Energy (au)  
0 -384.999806252  
1 -385.011491997  
2 -385.011738297  
3 -385.011750569  
4 -385.011751256  
5 -385.011751256  
6 -385.011751256  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.70823 0.12369323847
b 1.21582 0.04055538982
c 0.92084 0.03071591614

Partial Charges

Atom Symbol Charge
1 C -0.512181  
2 C 0.342427  
3 C 0.910400  
4 C 0.080281  
5 C -0.186908  
6 C -0.062802  
7 C -0.277571  
8 C -0.752718  
9 H 0.095620  
10 H 0.087856  
11 H 0.090329  
12 H 0.090403  
13 H 0.127730  
14 O -0.462215  
15 H 0.151196  
16 H 0.139075  
17 H 0.139075  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A" 54.2138 3.8274
2 A" 149.9540 0.0336
3 A" 152.4692 0.0021
4 A' 217.9731 5.3000
5 A' 365.0631 0.6886
6 A" 411.8849 0.0041
7 A" 428.9484 0.3402
8 A' 465.2012 0.7925
9 A' 596.5662 24.9713
10 A" 602.0380 12.4836
11 A' 634.1178 0.9569
12 A" 702.6841 39.1712
13 A' 741.8874 0.5484
14 A" 773.4054 35.3695
15 A" 860.3668 0.2255
16 A" 945.0779 2.2178
17 A' 956.6655 36.3613
18 A" 990.7940 0.2729
19 A" 1008.6108 0.2675
20 A' 1020.2293 0.8044
21 A' 1045.5770 6.2008
22 A" 1048.1819 0.6979
23 A' 1092.6752 1.4549
24 A' 1106.0394 5.6648
25 A' 1185.0139 0.7915
26 A' 1201.8635 16.4100
27 A' 1273.1767 177.5335
28 A' 1332.2283 7.8289
29 A' 1354.4905 1.9822
30 A' 1388.0956 46.5570
31 A' 1470.4296 12.0651
32 A" 1480.0004 10.7977
33 A' 1483.2616 16.3117
34 A' 1525.9571 0.4977
35 A' 1617.8624 9.6623
36 A' 1636.5497 23.2271
37 A' 1739.1608 203.9046
38 A' 3032.9221 2.8179
39 A" 3087.8676 6.9038
40 A' 3139.7765 11.0829
41 A' 3162.8212 0.0743
42 A' 3173.0280 8.0250
43 A' 3182.7834 15.8072
44 A' 3192.6133 9.0012
45 A' 3197.7561 5.4578
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

IT PROBABLY IS NOT POSSIBLE FOR A SCIENTIST TO INTERROGATE NATURE FROM A WHOLLY DISINTERESTED VIEWPOINT. EVEN IF HE HAS NO PARTICULAR AXE TO GRIND, HE IS LIKELY TO HAVE A DISTINCTIVE WAY OF VIEWING NATURE. -- JOHN LOSEE