WebMO Job Summary

123272: C4H4O4 maleic acid C2, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C4H4O4
Symmetry C2
Basis 6-31G(d)
RB3LYP Energy -455.718617903 Hartree
ZPE 0.082627 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -455.628261 Hartree
Enthalpy -455.627317 Hartree
Free Energy -455.669688 Hartree
Cv 26.437 cal/mol-K
Entropy 89.178 cal/mol-K
Dipole Moment 0.6444 Debye
Server batch (125574)
CPU time 302.3 sec

Geometry Sequence Energies

Step Energy  
0 -455.718616979  
1 -455.718617794  
2 -455.718616421  
3 -455.718617903  
4 -455.718617903  
5 -455.718617903  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.47469 0.14925959211
b 1.32149 0.04408016162
c 1.17423 0.03916809675

Partial Charges

Atom Symbol Charge
1 C -0.140387  
2 C -0.140387  
3 C 0.554677  
4 O -0.556682  
5 H 0.413570  
6 O -0.453731  
7 H 0.182552  
8 C 0.554677  
9 O -0.556682  
10 H 0.413570  
11 O -0.453731  
12 H 0.182552  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 B 12.9589 5.7162
2 A 64.9987 1.6251
3 A 170.2312 0.0027
4 A 235.2850 1.5872
5 B 266.3006 3.7308
6 A 467.8814 0.7593
7 B 470.8626 34.3834
8 A 565.7847 70.5346
9 B 575.8154 50.3993
10 A 626.2691 14.3498
11 B 644.2224 125.9345
12 B 774.2697 8.8994
13 A 780.2891 4.3334
14 A 832.2205 7.0073
15 B 833.8790 84.8960
16 B 939.2997 41.6048
17 A 1011.0962 0.0042
18 A 1175.7533 235.9379
19 B 1202.5248 139.0699
20 A 1260.7157 69.2654
21 B 1365.0566 24.3932
22 A 1412.5004 91.7785
23 B 1432.3398 25.6149
24 A 1705.8360 19.9049
25 B 1829.7118 618.7379
26 A 1835.4311 11.0380
27 B 3196.6898 0.5225
28 A 3213.0071 1.5656
29 B 3683.5737 37.1324
30 A 3684.3707 80.8288
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

PERICLES, SOPHOCLES, PELOPONESIAN WAR, FRENCH VERBS, LATIN VERBS H2SO4.