WebMO Job Summary

123274: C4H3O4(-1) malate, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C4H3O4(1-)
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -455.152436159 Hartree
ZPE 0.069095 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -455.077487 Hartree
Enthalpy -455.076543 Hartree
Free Energy -455.113839 Hartree
Cv 21.200 cal/mol-K
Entropy 78.496 cal/mol-K
Dipole Moment 6.1533 Debye
Server batch (125576)
CPU time 690.6 sec

Geometry Sequence Energies

Step Energy  
0 -454.817712142  
1 -455.055177042  
2 -455.134913198  
3 -455.121998903  
4 -455.148803820  
5 -455.150708320  
6 -455.151490054  
7 -455.151935473  
8 -455.152213203  
9 -455.152362126  
10 -455.152421078  
11 -455.152433864  
12 -455.152436159  
13 -455.152436159  
14 -455.152436159  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 5.37106 0.17915927692
b 1.18289 0.03945696326
c 0.96939 0.03233536982

Partial Charges

Atom Symbol Charge
1 C -0.136898  
2 C -0.191129  
3 C 0.548778  
4 O -0.528448  
5 H 0.368005  
6 O -0.544326  
7 H 0.100653  
8 C 0.513264  
9 O -0.627911  
10 O -0.600624  
11 H 0.098638  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" -86.7788 0.2352
2 A" -13.1060 8.3218
3 A' 171.7576 5.9770
4 A' 225.1821 1.6163
5 A" 255.4306 7.4914
6 A' 389.4587 0.2447
7 A" 556.4554 7.7532
8 A' 566.0712 41.0537
9 A' 611.7184 23.8330
10 A" 662.6714 72.4460
11 A' 765.7005 19.9880
12 A" 793.6289 6.5872
13 A' 823.6565 47.3898
14 A" 863.5514 55.3317
15 A' 917.4510 28.6128
16 A" 1026.6576 1.1378
17 A' 1199.0591 205.6799
18 A' 1269.5592 34.9140
19 A' 1316.4386 210.6264
20 A' 1413.8663 9.6887
21 A' 1426.9720 62.3622
22 A' 1640.8857 28.7776
23 A' 1746.7949 385.6962
24 A' 1758.4914 339.4083
25 A' 3115.9554 22.8607
26 A' 3150.4720 52.6385
27 A' 3661.2897 7.5796
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THE TEST OF A FIRST RATE INTELLIGENCE IS THE ABILITY TO HOLD TWO OPPOSED IDEAS IN THE MIND AT THE SAME TIME, AND STILL RETAIN THE ABILITY TO FUNCTION. ONE SHOULD, FOR EXAMPLE, BE ABLE TO SEE THAT THINGS ARE HOPELESS AND YET BE DETERMINED TO MAKE THEM OTHERWISE. -- F. SCOTT FITZGERALD