WebMO Job Summary

123291: C4H3O4(-1) malate Cs, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C4H3O4(1-)
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -455.161691467 Hartree
ZPE 0.068865 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -455.085114 Hartree
Enthalpy -455.084170 Hartree
Free Energy -455.126807 Hartree
Cv 25.488 cal/mol-K
Entropy 89.738 cal/mol-K
Dipole Moment 4.6086 Debye
Server batch (125593)
CPU time 281.8 sec

Geometry Sequence Energies

Step Energy  
0 -455.161689237  
1 -455.161685707  
2 -455.161691467  
3 -455.161691467  
4 -455.161691467  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.48013 0.14944105098
b 1.25604 0.04189698461
c 1.17011 0.03903066834

Partial Charges

Atom Symbol Charge
1 C -0.140814  
2 C -0.187435  
3 C 0.553363  
4 O -0.562129  
5 H 0.374513  
6 O -0.555398  
7 H 0.087333  
8 C 0.520329  
9 O -0.596741  
10 O -0.596741  
11 H 0.103721  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 30.0898 0.0523
2 A" 58.7980 3.5853
3 A' 118.2320 7.3329
4 A" 192.5265 0.0355
5 A' 289.3621 0.4167
6 A" 389.5777 13.9405
7 A' 513.9840 22.6911
8 A" 583.2794 72.4782
9 A' 588.4017 28.4812
10 A' 617.6671 27.5980
11 A" 740.1351 2.8650
12 A' 805.2667 14.2829
13 A" 826.0184 53.5267
14 A' 845.4801 12.1987
15 A' 943.3196 32.2128
16 A" 976.5876 0.2617
17 A' 1176.6242 157.3170
18 A' 1240.3182 96.2957
19 A' 1353.6238 134.5405
20 A' 1404.2587 124.5338
21 A' 1440.4035 35.9566
22 A' 1616.3042 53.4234
23 A" 1746.5710 378.1464
24 A' 1767.8163 566.5521
25 A' 3103.1586 40.3797
26 A' 3157.7046 44.7731
27 A' 3702.6054 21.9439
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

I KNOW YOU BELIEVE YOU UNDERSTAND WHAT YOU THINK I SAID, BUT I AM NOT SURE YOU REALIZE THAT WHAT YOU HEARD IS NOT WHAT I MEANT.