WebMO Job Summary
123665: C15H12O2 diketone C1 (chloroform), NMR - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) NMR SCRF=(PCM,Solvent=chloroform) Geom=Connectivity
Method
B3LYP
Stoichiometry
C
15
H
12
O
2
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-729.493732163 Hartree
Dipole Moment
5.9046 Debye
Server
class (124449)
CPU time
3645.9 sec
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.1604781
0.03870938274
b
0.2197350
0.00732957065
c
0.2061557
0.00687661395
Partial Charges
Atom
Symbol
Charge
1
C
-0.486642
2
C
0.275275
3
C
1.059124
4
C
0.138637
5
C
-0.293465
6
C
-0.033368
7
C
-0.463510
8
C
-0.615730
9
H
0.118378
10
H
0.107097
11
H
0.109318
12
H
0.107719
13
H
0.128814
14
O
-0.453719
15
C
0.114684
16
C
0.915761
17
C
-0.630552
18
C
-0.318324
19
C
-0.049505
20
C
-0.241469
21
C
0.059415
22
H
0.127398
23
H
0.105942
24
H
0.107659
25
H
0.105003
26
H
0.117550
27
O
-0.466397
28
H
0.181065
29
H
0.173842
Absolute NMR Shifts
Atom
Symbol
Isotropic
Anisotropy
1
C*
53.5514
40.5371
2
C*
205.2233
164.0619
3
C*
141.4487
173.9494
4
C*
133.8309
200.9722
5
C*
134.1496
187.8836
6
C*
140.4433
196.6060
7
C*
133.6624
186.9672
8
C*
135.4645
187.3943
9
H*
8.4003
8.8181
10
H*
7.8871
5.6718
11
H*
8.0369
5.2982
12
H*
7.9055
5.4360
13
H*
8.5661
7.7306
14
O
-265.0456
949.0693
15
C*
205.5510
169.3180
16
C*
142.0072
178.2547
17
C*
136.3885
186.2836
18
C*
133.5312
185.9149
19
C*
139.9504
195.5195
20
C*
134.1897
187.2512
21
C*
134.0687
200.7484
22
H*
8.7059
7.1641
23
H*
7.8991
5.2958
24
H*
7.9565
5.3190
25
H*
7.7344
6.3368
26
H*
8.0704
8.7303
27
O
-281.7013
947.5621
28
H*
4.2140
4.3503
29
H*
5.5151
6.0984
*Denotes shift relative to TMS
TMS shielding (C)
TMS shielding (H)
1
H NMR Spectrum
13
C NMR Spectrum
Peak Width (ppm)
Simulate proton splitting
NMR Field
MHz
Proton-proton coupling
Hz
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