WebMO Job Summary
135321: C4H2O4(-2) fumarate, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
4
H
2
O
4
(2-)
Symmetry
C2H
Basis
6-311+G(2d,p)
RB3LYP Energy
-454.688836374 Hartree
ZPE
0.056018 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-454.625479 Hartree
Enthalpy
-454.624535 Hartree
Free Energy
-454.665558 Hartree
C
v
23.765 cal/mol-K
Entropy
86.340 cal/mol-K
Dipole Moment
0.0000 Debye
Server
class (136430)
CPU time
668.2 sec
Geometry Sequence Energies
Step
Energy (au)
0
-454.655578842
1
-454.682058700
2
-454.688285360
3
-454.688811968
4
-454.688833889
5
-454.688836374
6
-454.688836374
7
-454.688836374
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
5.83964
0.19478942329
b
0.96488
0.03218493242
c
0.82806
0.02762110847
Partial Charges
Atom
Symbol
Charge
1
C
-0.072451
2
C
-0.072451
3
C
0.353728
4
O
-0.686454
5
O
-0.680291
6
H
0.085467
7
C
0.353728
8
O
-0.686454
9
O
-0.680291
10
H
0.085467
Vibrational Modes
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Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
AU
35.8382
0.6246
2
BG
118.4448
0.0000
3
BU
137.7502
4.3269
4
AU
156.9838
17.9794
5
AG
261.6579
0.0000
6
AG
388.2181
0.0000
7
BU
556.4806
12.5083
8
BU
647.7322
49.8316
9
BG
663.3771
0.0000
10
AG
746.2585
0.0000
11
AU
820.5664
16.9166
12
BU
907.8668
41.8760
13
AG
935.9199
0.0000
14
BG
939.3016
0.0000
15
AU
1030.7650
38.9657
16
BU
1190.2311
23.2418
17
AG
1279.6916
0.0000
18
BU
1333.1979
690.2611
19
AG
1352.2953
0.0000
20
AG
1572.2862
0.0000
21
BU
1579.1958
1161.5311
22
AG
1664.0640
0.0000
23
AG
3133.2486
0.0000
24
BU
3137.8063
38.7686
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
"MATHEMATICS IS THE ART OF GIVING THE SAME NAME TO DIFFERENT THINGS." - H. POINCARE