WebMO Job Summary
135322: C4H2O4(-2) maleate, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
4
H
2
O
4
(2-)
Symmetry
C2V
Basis
6-311+G(2d,p)
RB3LYP Energy
-454.656842821 Hartree
ZPE
0.055475 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-454.595725 Hartree
Enthalpy
-454.594780 Hartree
Free Energy
-454.631239 Hartree
C
v
19.889 cal/mol-K
Entropy
76.733 cal/mol-K
Dipole Moment
3.5361 Debye
Server
class (136431)
CPU time
740.5 sec
Geometry Sequence Energies
Step
Energy (au)
0
-454.618053296
1
-454.647771712
2
-454.641396852
3
-454.656040256
4
-454.656775410
5
-454.656841005
6
-454.656842821
7
-454.656842821
8
-454.656842821
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
5.51186
0.18385585938
b
1.08825
0.03630011266
c
0.90882
0.03031497210
Partial Charges
Atom
Symbol
Charge
1
C
-0.149082
2
C
-0.149082
3
C
0.398513
4
O
-0.686128
5
O
-0.604720
6
H
0.041417
7
C
0.398513
8
O
-0.604720
9
O
-0.686128
10
H
0.041417
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A2
-73.3735
0.0000
2
B1
-60.4933
13.3943
3
A1
131.8924
0.8138
4
B2
250.4772
0.6005
5
A2
304.0343
0.0000
6
A1
381.2342
0.0000
7
B1
571.8506
0.0793
8
A1
586.7190
13.1842
9
B2
623.2942
22.4493
10
B2
784.8121
45.2734
11
A2
826.0450
0.0000
12
A1
827.4639
17.3869
13
B1
880.9984
41.7673
14
B2
927.9814
20.8082
15
A2
1038.8143
0.0000
16
B2
1275.0403
634.8232
17
A1
1286.0991
13.4609
18
A1
1308.7929
11.2341
19
B2
1403.2483
45.3634
20
B2
1599.2122
199.9175
21
A1
1600.8374
206.7115
22
A1
1640.9434
615.6362
23
B2
3027.8640
15.3315
24
A1
3073.2015
128.0092
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
IF THERE IS ONE WAY BETTER THAN ANOTHER IT IS THE WAY OF NATURE. -- ARISTOTLE