WebMO Job Summary
146498: C12H16O 4′-isobutylacetophenone conformer 2, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
12
H
16
O
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-542.316463668 Hartree
ZPE
0.249347 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-542.053552 Hartree
Enthalpy
-542.052608 Hartree
Free Energy
-542.108174 Hartree
C
v
50.835 cal/mol-K
Entropy
116.949 cal/mol-K
Dipole Moment
3.7263 Debye
Server
class (147470)
CPU time
17412.9 sec
Geometry Sequence Energies
Step
Energy (au)
0
-542.314917045
1
-542.316303816
2
-542.316431380
3
-542.316203432
4
-542.316458832
5
-542.316463029
6
-542.316463479
7
-542.316463579
8
-542.316463668
9
-542.316463668
10
-542.316463668
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.25393
0.07518301211
b
0.33379
0.01113403593
c
0.31567
0.01052961779
Partial Charges
Atom
Symbol
Charge
1
C
-0.821366
2
C
1.034252
3
C
-0.528750
4
C
-0.755779
5
C
0.904242
6
C
-0.159607
7
C
-0.151722
8
H
0.084668
9
H
0.125420
10
C
0.268430
11
C
-0.506429
12
H
0.149814
13
H
0.139922
14
H
0.139552
15
O
-0.470515
16
H
0.093687
17
H
0.082163
18
C
0.448451
19
C
-0.521897
20
H
0.132317
21
H
0.117496
22
H
0.114721
23
C
-0.568121
24
H
0.116738
25
H
0.119005
26
H
0.119164
27
H
0.060158
28
H
0.117316
29
H
0.116670
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
34.4586
1.5691
2
A
51.1954
0.0644
3
A
58.3544
2.0875
4
A
67.9623
0.9666
5
A
143.2745
0.3220
6
A
148.8368
0.0130
7
A
192.4953
4.4481
8
A
225.8890
0.0252
9
A
246.8760
0.0473
10
A
274.9929
0.2140
11
A
282.7591
0.6224
12
A
348.4366
0.6221
13
A
376.3560
0.7144
14
A
399.9656
0.8121
15
A
417.5942
0.0071
16
A
425.9325
1.1394
17
A
471.9445
1.7681
18
A
513.6436
6.1897
19
A
591.5173
15.6439
20
A
608.0588
20.2772
21
A
653.1861
0.4368
22
A
699.7331
8.6755
23
A
752.2141
0.4112
24
A
804.3180
14.9888
25
A
836.1104
1.0747
26
A
851.3153
3.4551
27
A
871.0339
18.4113
28
A
894.0784
3.1432
29
A
933.2064
1.7393
30
A
950.3189
2.3688
31
A
958.3866
45.7140
32
A
967.3358
0.0451
33
A
974.0550
0.0623
34
A
1000.0043
0.4137
35
A
1037.1074
5.8868
36
A
1048.1769
0.7199
37
A
1090.5131
1.7526
38
A
1098.4250
4.6463
39
A
1131.8399
2.7636
40
A
1146.3780
4.3620
41
A
1188.3655
15.5858
42
A
1206.1417
40.2788
43
A
1224.7022
5.9475
44
A
1245.2722
0.5710
45
A
1277.6555
200.5820
46
A
1316.1730
4.2091
47
A
1334.4723
10.3396
48
A
1345.8292
2.7564
49
A
1368.2495
2.2155
50
A
1371.2557
3.4618
51
A
1386.9666
44.1952
52
A
1403.7610
5.8016
53
A
1423.4650
6.2367
54
A
1446.1483
23.1071
55
A
1470.6317
12.4757
56
A
1480.1032
10.5952
57
A
1485.2112
0.8782
58
A
1490.4966
1.6681
59
A
1497.6471
2.9632
60
A
1505.0001
4.4344
61
A
1511.2045
13.1972
62
A
1541.2089
0.7295
63
A
1600.7390
12.1571
64
A
1642.6906
89.9873
65
A
1735.3084
223.0126
66
A
2997.5735
3.7671
67
A
3012.2351
7.3605
68
A
3013.9627
42.3333
69
A
3020.1548
43.9853
70
A
3032.6614
3.0750
71
A
3049.9101
14.8097
72
A
3070.5332
9.5578
73
A
3076.9197
54.7099
74
A
3082.1387
41.2104
75
A
3087.6211
7.3862
76
A
3092.7309
34.6412
77
A
3139.2196
13.4231
78
A
3155.7286
10.8792
79
A
3160.5467
11.8431
80
A
3187.2239
8.2232
81
A
3194.7270
2.7844
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
TO ERR IS HUMAN - AND TO BLAME IT ON A COMPUTER IS EVEN MORE SO.