WebMO Job Summary
147295: C8H9ONBr(+1) meta bromination arenium acetanilide, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
8
H
9
BrNO(1+)
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-3014.23052567 Hartree
ZPE
0.154750 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-3014.064447 Hartree
Enthalpy
-3014.063503 Hartree
Free Energy
-3014.116627 Hartree
C
v
39.999 cal/mol-K
Entropy
111.810 cal/mol-K
Dipole Moment
6.8367 Debye
Server
class (148189)
CPU time
19354.4 sec
Geometry Sequence Energies
Step
Energy (au)
0
-3014.22919730
1
-3014.23050977
2
-3014.23051339
3
-3014.23051412
4
-3014.23051623
5
-3014.23051654
6
-3014.23051677
7
-3014.23051713
8
-3014.23051744
9
-3014.23051797
10
-3014.23051838
11
-3014.23051896
12
-3014.23051956
13
-3014.23052042
14
-3014.23052120
15
-3014.23052183
16
-3014.23052235
17
-3014.23052318
18
-3014.23052363
19
-3014.23052302
20
-3014.23052426
21
-3014.23052464
22
-3014.23052500
23
-3014.23052249
24
-3014.23052460
25
-3014.20843375
26
-3014.23051648
27
-3014.23052534
28
-3014.23052550
29
-3014.23052559
30
-3014.23052563
31
-3014.23052566
32
-3014.23052567
33
-3014.23052567
34
-3014.23052567
35
-3014.23052567
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.43239
0.04777938743
b
0.42105
0.01404471623
c
0.34560
0.01152797513
Partial Charges
Atom
Symbol
Charge
1
C
-0.653329
2
C
0.692264
3
N
-0.381418
4
C
0.499452
5
C
-0.286722
6
C
-0.121419
7
C
-0.006427
8
C
-0.316238
9
C
0.197741
10
H
0.222545
11
Br
0.134138
12
H
0.214036
13
H
0.177025
14
H
0.151044
15
H
0.149629
16
H
0.253972
17
O
-0.430604
18
H
0.180934
19
H
0.155106
20
H
0.168272
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
23.2637
1.0123
2
A
26.9604
5.1144
3
A
54.7243
6.9007
4
A
81.1025
3.9630
5
A
109.6057
2.4717
6
A
173.9022
7.1390
7
A
258.5075
1.3138
8
A
289.6383
1.1386
9
A
335.3879
3.0895
10
A
356.9330
0.9636
11
A
413.0151
1.1756
12
A
493.9228
21.7931
13
A
514.8508
55.7925
14
A
530.1843
24.8028
15
A
603.2753
5.7824
16
A
611.9578
4.5945
17
A
646.0336
4.3327
18
A
665.6680
2.4985
19
A
800.9330
26.9525
20
A
824.8282
0.3530
21
A
911.1342
16.3730
22
A
933.3462
16.7517
23
A
955.7424
6.0290
24
A
987.4375
13.5866
25
A
999.8467
2.3045
26
A
1011.9072
45.6247
27
A
1030.4529
0.7972
28
A
1035.5758
21.4086
29
A
1061.5105
4.3273
30
A
1090.8133
1.2919
31
A
1163.7491
2.6288
32
A
1206.8531
16.8949
33
A
1222.5607
212.1287
34
A
1260.1898
54.1099
35
A
1328.6540
51.8141
36
A
1371.3324
91.8642
37
A
1404.5766
16.0600
38
A
1421.1728
289.0896
39
A
1463.9200
12.6646
40
A
1474.0305
157.6994
41
A
1481.4974
16.1545
42
A
1534.9446
200.7259
43
A
1588.9453
131.0958
44
A
1620.8499
53.8815
45
A
1782.7055
155.8372
46
A
3038.7166
3.6224
47
A
3068.0950
28.8147
48
A
3096.6791
1.3803
49
A
3158.5387
0.1889
50
A
3160.1966
1.2936
51
A
3200.2606
4.2846
52
A
3211.9775
11.3604
53
A
3233.9183
37.7141
54
A
3600.3774
52.1009
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
IF GOD HAD MEANT MAN TO SEE THE SUN RISE, HE WOULD HAVE SCHEDULED IT FOR A LATER HOUR.