WebMO Job Summary
147303: C9H11 3-propylbenzyl radical, Optimize + Vib Freq - Gaussian
Raw Output
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
9
H
11
(2)
Symmetry
C1
Basis
6-31G(d)
UB3LYP Energy
-349.521485835 Hartree
ZPE
0.170562 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-349.341845 Hartree
Enthalpy
-349.340901 Hartree
Free Energy
-349.386401 Hartree
C
v
33.693 cal/mol-K
Entropy
95.764 cal/mol-K
Dipole Moment
0.1568 Debye
Server
class (148197)
CPU time
3335.7 sec
Geometry Sequence Energies
Step
Energy (au)
0
-349.498190607
1
-349.513820463
2
-349.518425237
3
-349.519047342
4
-349.519126628
5
-349.519144615
6
-349.519147198
7
-349.519148192
8
-349.519148603
9
-349.519150199
10
-349.519152843
11
-349.519156530
12
-349.455961668
13
-349.519209313
14
-349.519272943
15
-349.518585097
16
-349.519487086
17
-349.519609016
18
-349.520687895
19
-349.521031068
20
-349.521173558
21
-349.521433240
22
-349.521464090
23
-349.521473493
24
-349.521475165
25
-349.521484941
26
-349.521485782
27
-349.521485835
28
-349.521485835
29
-349.521485835
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
4.40471
0.14692531058
b
0.87585
0.02921521128
c
0.78241
0.02609838837
Partial Charges
Atom
Symbol
Charge
1
C
-0.348733
2
C
0.170346
3
C
-0.180421
4
C
-0.127883
5
C
-0.131682
6
C
-0.127870
7
C
-0.181066
8
H
0.122154
9
H
0.127305
10
H
0.126820
11
H
0.127274
12
H
0.121327
13
C
-0.256958
14
C
-0.308116
15
H
0.142987
16
H
0.139979
17
H
0.150052
18
H
0.146411
19
H
0.146638
20
H
0.141436
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
37.29 (38.8462)
0.0326
2
A
84.84 (88.3780)
0.2285
3
A
100.44 (104.6244)
0.1453
4
A
113.07 (117.7815)
0.3226
5
A
270.39 (281.6572)
0.7529
6
A
303.41 (316.0548)
0.9187
7
A
331.13 (344.9263)
0.0511
8
A
400.57 (417.2556)
0.0036
9
A
442.04 (460.4563)
38.6384
10
A
490.84 (511.2901)
10.6081
11
A
576.31 (600.3201)
3.0484
12
A
611.30 (636.7662)
0.0371
13
A
687.33 (715.9675)
23.5178
14
A
715.03 (744.8182)
3.2618
15
A
734.96 (765.5820)
22.6204
16
A
795.25 (828.3830)
1.0361
17
A
825.82 (860.2312)
0.0053
18
A
853.67 (889.2398)
0.5087
19
A
886.15 (923.0753)
0.9074
20
A
925.75 (964.3280)
0.0139
21
A
951.26 (990.8944)
0.6244
22
A
955.82 (995.6470)
1.1512
23
A
977.59 (1018.3269)
0.2170
24
A
1016.57 (1058.9260)
2.1615
25
A
1033.01 (1076.0567)
1.7059
26
A
1047.48 (1091.1269)
1.9648
27
A
1080.76 (1125.7938)
1.8926
28
A
1137.43 (1184.8274)
1.6299
29
A
1144.58 (1192.2752)
0.0154
30
A
1165.00 (1213.5401)
0.0902
31
A
1184.08 (1233.4203)
0.8523
32
A
1248.48 (1300.5034)
0.6874
33
A
1269.83 (1322.7427)
2.3393
34
A
1306.76 (1361.2059)
0.0870
35
A
1316.09 (1370.9244)
0.5035
36
A
1334.95 (1390.5740)
0.0931
37
A
1426.70 (1486.1474)
1.0717
38
A
1438.74 (1498.6857)
1.2200
39
A
1441.52 (1501.5784)
4.7079
40
A
1464.08 (1525.0787)
2.3158
41
A
1485.01 (1546.8839)
10.7335
42
A
1578.02 (1643.7709)
0.8750
43
A
1598.92 (1665.5466)
5.3511
44
A
2827.21 (2945.0097)
25.1804
45
A
2916.48 (3037.9959)
13.0957
46
A
2926.43 (3048.3597)
34.5487
47
A
2961.31 (3084.6950)
27.8003
48
A
3034.96 (3161.4183)
22.2680
49
A
3043.14 (3169.9386)
11.2236
50
A
3044.79 (3171.6527)
6.7314
51
A
3057.49 (3184.8859)
7.3251
52
A
3066.03 (3193.7804)
44.3254
53
A
3078.25 (3206.5154)
22.6957
54
A
3129.14 (3259.5165)
18.1860
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
"IF I COULD JUST GET IT ON PAPER" LIFE AND INK, THEY RUN OUT AT THE SAME TIME, OR SO SAID MY OLD FRIEND THE SQUID. -- JIMMY BUFFETT, 1981