WebMO Job Summary

152938: C5H9OCl ax C1, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C5H9ClO
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -731.374863741 Hartree
ZPE 0.138251 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -731.230107 Hartree
Enthalpy -731.229163 Hartree
Free Energy -731.267450 Hartree
Cv 24.753 cal/mol-K
Entropy 80.584 cal/mol-K
Dipole Moment 2.8951 Debye
Server batch (155381)
CPU time 1167.3 sec

Geometry Sequence Energies

Step Energy  
0 -730.653899683  
1 -730.982272872  
2 -731.261068452  
3 -731.250101171  
4 -731.303477866  
5 -731.340622091  
6 -731.367255637  
7 -731.372567813  
8 -731.374212757  
9 -731.374646554  
10 -731.374826741  
11 -731.374861336  
12 -731.374863741  
13 -731.374863741  
14 -731.374863741  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.37784 0.11267261433
b 1.75729 0.05861688489
c 1.51130 0.05041154171

Partial Charges

Atom Symbol Charge
1 C -0.273085  
2 C 0.032784  
3 O -0.426760  
4 C -0.042239  
5 C -0.282258  
6 C -0.274861  
7 H 0.145360  
8 H 0.162534  
9 H 0.144909  
10 H 0.144606  
11 H 0.161766  
12 H 0.156457  
13 Cl -0.161653  
14 H 0.193041  
15 H 0.153297  
16 H 0.166101  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 134.6378 2.6573
2 A 191.6436 2.9227
3 A 290.3443 6.7712
4 A 357.3870 1.9705
5 A 390.8591 5.3317
6 A 455.9772 8.3244
7 A 501.0446 22.5929
8 A 552.4192 74.9742
9 A 709.1584 50.9465
10 A 826.3308 20.2134
11 A 846.3272 4.9058
12 A 886.6270 18.8890
13 A 896.5811 19.9407
14 A 940.7878 2.5933
15 A 1025.4990 29.8252
16 A 1063.4494 13.7339
17 A 1072.5780 17.6278
18 A 1118.2527 14.6321
19 A 1162.5183 96.7424
20 A 1215.4270 3.2893
21 A 1233.8703 91.4696
22 A 1291.2622 15.8958
23 A 1300.5539 27.8008
24 A 1323.1887 5.1168
25 A 1376.4184 2.1634
26 A 1391.5759 6.9728
27 A 1404.4815 0.5345
28 A 1412.8213 2.1796
29 A 1441.4535 8.6378
30 A 1501.7999 2.3563
31 A 1511.0935 5.2857
32 A 1522.6659 5.7948
33 A 1536.5371 3.9638
34 A 3036.4782 16.0987
35 A 3044.4554 24.7893
36 A 3056.3309 18.7496
37 A 3059.7543 20.0874
38 A 3088.8070 32.9383
39 A 3102.7081 42.1737
40 A 3121.1506 16.1967
41 A 3132.6212 32.1629
42 A 3157.3802 18.2182
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THERE ARE PEOPLE SO ADDICTED TO EXAGERATING THEY CAN'T TELL THE TRUTH WITHOUT LYING. -- FORTUNE COOKIE