WebMO Job Summary

152939: C5H9OBr ax C1, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C5H9BrO
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -2842.88634069 Hartree
ZPE 0.137726 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -2842.741935 Hartree
Enthalpy -2842.740991 Hartree
Free Energy -2842.780513 Hartree
Cv 25.091 cal/mol-K
Entropy 83.182 cal/mol-K
Dipole Moment 2.9240 Debye
Server batch (155382)
CPU time 1272.5 sec

Geometry Sequence Energies

Step Energy  
0 -2842.50222205  
1 -2842.72677173  
2 -2842.86606456  
3 -2842.84902195  
4 -2842.87245078  
5 -2842.88128082  
6 -2842.88576130  
7 -2842.88625980  
8 -2842.88633242  
9 -2842.88633958  
10 -2842.88634069  
11 -2842.88634069  
12 -2842.88634069  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.18907 0.10637592491
b 1.16589 0.03888990430
c 1.07101 0.03572504816

Partial Charges

Atom Symbol Charge
1 C -0.276062  
2 C 0.108928  
3 O -0.427930  
4 C -0.046046  
5 C -0.282697  
6 C -0.277908  
7 H 0.145019  
8 H 0.164716  
9 H 0.145057  
10 H 0.145704  
11 H 0.163618  
12 H 0.156915  
13 Br -0.224823  
14 H 0.186923  
15 H 0.151635  
16 H 0.166951  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 118.6907 2.3788
2 A 181.1513 2.1040
3 A 256.8789 7.0750
4 A 338.5356 1.0861
5 A 361.6142 4.0819
6 A 453.1263 9.3597
7 A 490.7266 25.8068
8 A 538.9954 52.4752
9 A 694.1797 42.4853
10 A 826.2501 18.6456
11 A 844.0506 2.3768
12 A 885.1748 16.6926
13 A 897.9470 23.9153
14 A 934.7692 1.7351
15 A 1023.6511 34.3806
16 A 1062.4272 12.9788
17 A 1070.6158 28.5765
18 A 1099.3219 18.3283
19 A 1161.9392 111.7238
20 A 1200.6310 22.2049
21 A 1225.4047 54.6516
22 A 1272.4359 51.7310
23 A 1297.2531 19.3140
24 A 1322.9677 4.7023
25 A 1374.6590 1.6974
26 A 1389.5913 9.0955
27 A 1403.1523 0.9544
28 A 1410.9892 1.3490
29 A 1441.9873 8.5339
30 A 1498.9574 2.7497
31 A 1511.3033 4.9859
32 A 1520.1004 6.9034
33 A 1535.7052 7.2024
34 A 3027.8580 19.6591
35 A 3043.9076 25.5638
36 A 3055.0169 16.3660
37 A 3060.5768 18.4473
38 A 3089.4853 33.0538
39 A 3104.5628 38.3223
40 A 3123.5502 13.4037
41 A 3134.8829 32.1390
42 A 3169.7054 12.7689
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

HICKORY, DICKORY, DOCK TWO MICE RAN UP THE CLOCK THE CLOCK STRUCK ONE... THE OTHER ESCAPED WITH MINOR INJURIES.