WebMO Job Summary

154580: C9H12O2N ortho 1, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C9H12NO2(1+)
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -554.977440655 Hartree
ZPE 0.198634 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -554.766745 Hartree
Enthalpy -554.765801 Hartree
Free Energy -554.817721 Hartree
Cv 44.309 cal/mol-K
Entropy 109.276 cal/mol-K
Dipole Moment 4.8158 Debye
Server chem344 (727564)
CPU time 6810.7 sec

Geometry Sequence Energies

Step Energy  
0 -554.710422283  
1 -554.889552780  
2 -554.940083876  
3 -554.937821631  
4 -554.960982557  
5 -554.967414790  
6 -554.962569514  
7 -554.968208149  
8 -554.971179780  
9 -554.972578677  
10 -554.973982128  
11 -554.974972848  
12 -554.976141759  
13 -554.976906343  
14 -554.977069525  
15 -554.977062731  
16 -554.977142950  
17 -554.977174818  
18 -554.977213323  
19 -554.977262832  
20 -554.977319807  
21 -554.977348813  
22 -554.977363073  
23 -554.977374191  
24 -554.977410486  
25 -554.977431718  
26 -554.977437021  
27 -554.977438850  
28 -554.977440267  
29 -554.977440655  
30 -554.977440655  
31 -554.977440655  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1.22681 0.04092197676
b 0.90293 0.03011850285
c 0.69272 0.02310665200

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 37.3541 8.5461
2 A 46.0896 3.6874
3 A 63.2733 5.5351
4 A 119.9465 3.4177
5 A 159.4174 2.1065
6 A 213.1987 14.3500
7 A 238.3625 32.8052
8 A 256.1712 1.9343
9 A 280.9329 4.0857
10 A 285.7693 26.8932
11 A 324.6901 2.9183
12 A 363.5684 5.9568
13 A 370.8730 37.8302
14 A 465.7999 2.2587
15 A 488.1746 27.8309
16 A 549.3331 20.0901
17 A 615.1199 6.1236
18 A 667.2764 21.2561
19 A 704.0421 46.9390
20 A 760.5531 112.5947
21 A 780.2286 1.6331
22 A 806.2870 104.9161
23 A 869.1711 28.7049
24 A 912.3792 2.3807
25 A 952.1041 1.8745
26 A 969.4347 10.1021
27 A 976.4077 6.1799
28 A 1013.0909 2.6469
29 A 1028.5393 3.0065
30 A 1043.9732 11.0782
31 A 1054.6929 3.6232
32 A 1084.5568 33.7064
33 A 1107.2274 0.3540
34 A 1135.5842 51.9399
35 A 1169.4080 8.4717
36 A 1202.3069 47.3009
37 A 1215.1649 1.8915
38 A 1228.2023 3.4545
39 A 1304.7446 7.4611
40 A 1328.4258 78.6652
41 A 1357.9129 243.6163
42 A 1393.6560 9.4794
43 A 1425.3447 15.8071
44 A 1426.3863 4.9312
45 A 1452.2293 14.9331
46 A 1462.5007 43.4666
47 A 1509.5242 160.4420
48 A 1512.8542 76.6300
49 A 1524.9131 45.2432
50 A 1535.4281 29.9630
51 A 1539.0755 30.2061
52 A 1562.3473 14.7100
53 A 1666.9139 80.9292
54 A 1777.4513 211.1252
55 A 3044.2146 3.2945
56 A 3062.1116 8.0086
57 A 3071.0699 6.3924
58 A 3131.3538 10.2998
59 A 3146.4339 2.7383
60 A 3151.2834 10.0203
61 A 3153.3857 4.6789
62 A 3197.0862 8.1705
63 A 3210.6255 0.1496
64 A 3220.5347 0.9802
65 A 3222.5405 2.8354
66 A 3241.3418 2.2227
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

YOU KNOW YOU'VE SPOKEN TOO LONG WHEN THE AUDIENCE STOPS LOOKING AT THEIR WATCHES AND STARTS SHAKING THEM.