WebMO Job Summary

154582: C9H12O2N para, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C9H12NO2(1+)
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -554.985219914 Hartree
ZPE 0.198469 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -554.774884 Hartree
Enthalpy -554.773939 Hartree
Free Energy -554.826349 Hartree
Cv 43.830 cal/mol-K
Entropy 110.305 cal/mol-K
Dipole Moment 4.7323 Debye
Server chem344 (727566)
CPU time 5295 sec

Geometry Sequence Energies

Step Energy  
0 -554.906467973  
1 -554.957150309  
2 -554.959519272  
3 -554.982275921  
4 -554.983700471  
5 -554.974858474  
6 -554.983929786  
7 -554.984703337  
8 -554.984937547  
9 -554.985024459  
10 -554.985079453  
11 -554.985118807  
12 -554.985133168  
13 -554.985135556  
14 -554.985137070  
15 -554.985138724  
16 -554.985141760  
17 -554.985147899  
18 -554.985154761  
19 -554.985161629  
20 -554.985185253  
21 -554.985185787  
22 -554.985207034  
23 -554.985208076  
24 -554.985218698  
25 -554.985219573  
26 -554.985218977  
27 -554.985219932  
28 -554.985219914  
29 -554.985219914  
30 -554.985219914  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.38297 0.07948732319
b 0.46663 0.01556510137
c 0.43119 0.01438295022

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 24.1931 0.7166
2 A 34.3372 0.0612
3 A 52.6992 3.1666
4 A 138.6117 0.9476
5 A 169.3706 3.2895
6 A 221.0492 1.1175
7 A 251.4586 0.0935
8 A 254.3113 2.2429
9 A 278.1234 4.4344
10 A 292.6251 0.7760
11 A 353.8735 0.1864
12 A 362.2383 6.5775
13 A 462.6409 0.6493
14 A 490.6698 1.0678
15 A 531.4767 1.3546
16 A 587.0182 1.3997
17 A 601.7140 4.1055
18 A 644.4614 37.9291
19 A 742.4965 8.8157
20 A 793.3443 1.1611
21 A 801.0614 46.2514
22 A 831.9369 100.4159
23 A 864.7774 61.2372
24 A 895.1318 36.5845
25 A 910.1248 155.9826
26 A 954.8406 5.4546
27 A 973.9178 5.4906
28 A 994.1768 16.0322
29 A 1007.9032 1.9900
30 A 1038.9394 22.3524
31 A 1054.9319 95.0020
32 A 1073.9027 12.0946
33 A 1096.3937 9.4429
34 A 1146.8505 93.6414
35 A 1150.4461 11.0679
36 A 1178.2778 2.4363
37 A 1217.1162 47.1029
38 A 1248.9658 11.8527
39 A 1301.6073 12.6979
40 A 1325.6499 11.1408
41 A 1361.4737 2.0036
42 A 1384.8923 256.1110
43 A 1416.0607 8.1931
44 A 1429.3102 4.8271
45 A 1450.2669 7.8798
46 A 1482.7119 79.8837
47 A 1497.8068 37.1794
48 A 1508.3532 5.8965
49 A 1511.9471 0.7538
50 A 1530.2378 19.9343
51 A 1536.3026 16.1139
52 A 1559.0212 57.8439
53 A 1665.0382 252.8353
54 A 1732.1434 237.9885
55 A 2959.0204 44.6681
56 A 3065.4457 5.9783
57 A 3068.0770 4.6589
58 A 3074.1932 6.3257
59 A 3141.3615 7.2678
60 A 3147.9943 10.0843
61 A 3149.1215 5.5999
62 A 3149.9813 9.3240
63 A 3220.3585 1.0206
64 A 3234.9093 6.7234
65 A 3241.5976 14.4475
66 A 3246.3680 6.0304
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

... THIS SEEMS PLAINLY ABSURD; BUT WHOEVER WISHES TO BECOME A PHILOSOPHER MUST LEARN NOT TO BE FRIGHTENED BY ABSURDITIES. -- BERTRAND RUSSELL