WebMO Job Summary
198784: C6H4O2NCl ortho-chloronitrobenzene, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
6
H
4
ClNO
2
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-896.498907879 Hartree
ZPE
0.092950 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-896.397901 Hartree
Enthalpy
-896.396957 Hartree
Free Energy
-896.440062 Hartree
C
v
29.573 cal/mol-K
Entropy
90.722 cal/mol-K
Dipole Moment
5.0259 Debye
Server
class (199790)
CPU time
7800.3 sec
Geometry Sequence Energies
Step
Energy (au)
0
-895.677098378
1
-895.946934358
2
-896.247917316
3
-896.311686247
4
-896.426380000
5
-896.422439415
6
-896.485948226
7
-896.493798124
8
-896.497200422
9
-896.466513757
10
-896.498574817
11
-896.498843029
12
-896.498905870
13
-896.498907656
14
-896.498907879
15
-896.498907879
16
-896.498907879
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.50526
0.05021006899
b
1.21907
0.04066379815
c
0.70413
0.02348724864
Partial Charges
Atom
Symbol
Charge
1
C
-0.142085
2
C
-0.871942
3
C
2.008793
4
C
-1.021184
5
C
-0.051020
6
C
-0.170601
7
H
0.100552
8
H
0.102313
9
H
0.127714
10
Cl
-0.010812
11
N
0.106269
12
O
-0.160695
13
O
-0.148342
14
H
0.131041
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
50.2034
0.4054
2
A
120.3852
0.5165
3
A
193.9932
1.1168
4
A
205.4219
0.1133
5
A
308.0521
0.4987
6
A
360.7904
0.9051
7
A
420.3773
0.7430
8
A
457.2775
6.6109
9
A
492.1174
4.9316
10
A
579.5787
1.0090
11
A
665.1676
9.0395
12
A
716.4869
8.5473
13
A
739.1195
17.5697
14
A
757.0560
54.1245
15
A
799.1086
10.7555
16
A
867.8252
29.6249
17
A
889.0632
0.1852
18
A
970.7625
2.0877
19
A
999.6500
0.3244
20
A
1058.7381
9.5548
21
A
1074.2321
31.3996
22
A
1143.0370
11.4268
23
A
1167.0923
3.7777
24
A
1189.9922
0.3001
25
A
1286.2960
5.3101
26
A
1326.6969
5.0011
27
A
1379.8429
221.2203
28
A
1473.5133
4.4864
29
A
1498.7095
26.5143
30
A
1578.3204
242.5841
31
A
1615.3653
25.5554
32
A
1627.9618
57.1060
33
A
3179.4342
2.0295
34
A
3193.9758
4.2533
35
A
3203.3396
0.8391
36
A
3211.4642
1.7858
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
HERE WE GO...... SLIDING DOWN THE RAZOR BLADE OF LIFE...... TOM LEHRER