WebMO Job Summary
199047: C15H14O Suzuki 4-methylboronic acid & 4′-bromoacetophenone, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
15
H
14
O
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-655.459123345 Hartree
ZPE
0.244844 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-655.199793 Hartree
Enthalpy
-655.198849 Hartree
Free Energy
-655.257673 Hartree
C
v
55.034 cal/mol-K
Entropy
123.807 cal/mol-K
Dipole Moment
4.0132 Debye
Server
class (200115)
CPU time
43146.4 sec
Geometry Sequence Energies
Step
Energy (au)
0
-655.397989160
1
-655.447358957
2
-655.458635694
3
-655.459014666
4
-655.459098661
5
-655.459102066
6
-655.459114538
7
-655.459118816
8
-655.459119867
9
-655.459120038
10
-655.459120157
11
-655.459120257
12
-655.459120408
13
-655.459120619
14
-655.459120962
15
-655.459121383
16
-655.459121824
17
-655.459122222
18
-655.459122684
19
-655.459122888
20
-655.459123004
21
-655.459123183
22
-655.459123295
23
-655.459123343
24
-655.459123345
25
-655.459123345
26
-655.459123345
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.23427
0.07452722510
b
0.20199
0.00673766116
c
0.18877
0.00629668943
Partial Charges
Atom
Symbol
Charge
1
C
-0.498822
2
C
0.645755
3
C
-0.439649
4
C
-0.516707
5
C
1.088123
6
C
0.760605
7
C
-0.413646
8
C
-0.128508
9
C
0.857992
10
C
-0.756315
11
C
-0.646685
12
H
0.091437
13
H
0.093829
14
C
0.390081
15
O
-0.469037
16
C
-0.511151
17
H
0.140572
18
H
0.150044
19
H
0.140692
20
H
0.125330
21
H
0.093500
22
C
-0.552733
23
C
-0.381767
24
H
0.081059
25
H
0.090817
26
H
0.093087
27
H
0.081726
28
H
0.123690
29
H
0.142799
30
H
0.123879
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
24.9568
0.3217
2
A
43.2748
0.6913
3
A
45.9008
2.6182
4
A
72.4141
0.1901
5
A
74.4484
1.4954
6
A
131.5488
1.4677
7
A
147.8662
0.0205
8
A
189.7825
2.5749
9
A
230.4322
1.6819
10
A
233.9246
1.2615
11
A
312.1510
0.4962
12
A
354.3079
0.5560
13
A
399.9046
0.5719
14
A
416.4242
0.9268
15
A
420.2826
6.1632
16
A
421.8991
0.4025
17
A
478.2224
7.2142
18
A
509.9800
6.7250
19
A
548.3359
6.3532
20
A
581.7362
10.8715
21
A
606.7445
12.6982
22
A
643.9014
15.2220
23
A
647.8785
2.8427
24
A
661.0877
0.5766
25
A
731.8979
0.2427
26
A
758.0234
2.4806
27
A
767.9789
4.2112
28
A
822.6384
8.5513
29
A
827.5088
58.3672
30
A
848.5110
0.5602
31
A
851.6572
1.9653
32
A
873.6181
13.9842
33
A
957.7804
60.1864
34
A
966.6866
0.5117
35
A
976.1784
0.1457
36
A
977.6597
1.0455
37
A
1001.8329
0.5739
38
A
1008.6342
0.0129
39
A
1026.3441
13.8382
40
A
1037.0346
0.3036
41
A
1046.7811
0.1250
42
A
1048.1174
0.7246
43
A
1064.0502
14.2961
44
A
1093.8339
2.1720
45
A
1140.7197
4.9230
46
A
1144.3211
4.8498
47
A
1207.7435
32.8723
48
A
1213.5109
29.0799
49
A
1232.1555
0.3381
50
A
1277.4478
265.4814
51
A
1291.0023
11.3785
52
A
1304.2636
0.1126
53
A
1321.0339
6.9805
54
A
1341.4382
7.9484
55
A
1348.5922
1.2894
56
A
1386.9105
48.9176
57
A
1416.2020
0.0817
58
A
1428.3269
17.7950
59
A
1449.4417
12.2227
60
A
1470.5568
13.0676
61
A
1480.1170
10.5771
62
A
1489.8033
6.7196
63
A
1493.0367
9.2396
64
A
1533.3473
5.6536
65
A
1555.2557
17.8420
66
A
1584.6634
12.9382
67
A
1607.2478
5.8556
68
A
1638.7297
158.3917
69
A
1651.0955
1.6334
70
A
1734.0363
249.4158
71
A
3020.6312
33.9224
72
A
3032.5599
3.0419
73
A
3072.7362
17.9153
74
A
3087.4768
7.1668
75
A
3099.2817
14.1805
76
A
3139.3681
14.9411
77
A
3154.4922
14.0208
78
A
3155.0465
19.5083
79
A
3171.3974
5.6672
80
A
3172.4305
4.0516
81
A
3177.3025
13.1012
82
A
3179.0915
3.4614
83
A
3190.5635
9.4145
84
A
3196.4650
2.3130
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
ALMOST ANYTHING IS EASIER TO GET INTO THAN OUT OF. -- AGNES ALLEN'S LAW FROM PAUL DICKSON'S "THE OFFICIAL RULES"