WebMO Job Summary

199217: C7H12O (S)-2-methylcyclohexanone, Optimize + Vib Freq - Gaussian

Calculated Quantities

Expand all

Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ
Method B3LYP
Stoichiometry C7H12O
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -349.314620528 Hartree
ZPE 0.178220 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -349.128464 Hartree
Enthalpy -349.127520 Hartree
Free Energy -349.168545 Hartree
Cv 30.499 cal/mol-K
Entropy 86.345 cal/mol-K
Dipole Moment 3.2406 Debye
Server class (200280)
CPU time 5340.8 sec

Geometry Sequence Energies

Step Energy (au)  
0 -349.310401619  
1 -349.314407887  
2 -349.313909646  
3 -349.314595190  
4 -349.314614437  
5 -349.314619681  
6 -349.314620471  
7 -349.314620528  
8 -349.314620528  
9 -349.314620528  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.86440 0.09554609943
b 1.99124 0.06642061689
c 1.28833 0.04297406308

Partial Charges

Atom Symbol Charge
1 C -0.201992  
2 C -0.296803  
3 C -0.162249  
4 C -0.341632  
5 C 0.393778  
6 C 0.221480  
7 C -0.544137  
8 H 0.135299  
9 H 0.114153  
10 H 0.138294  
11 H 0.087280  
12 O -0.449465  
13 H 0.123248  
14 H 0.132118  
15 H 0.111850  
16 H 0.107522  
17 H 0.104730  
18 H 0.110429  
19 H 0.110327  
20 H 0.105770  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A 84.6888 2.7869
2 A 149.8989 0.6045
3 A 196.7588 0.0867
4 A 279.2581 3.9783
5 A 305.6011 0.2231
6 A 323.9013 0.4266
7 A 393.9938 3.4168
8 A 428.7033 0.7702
9 A 501.5142 2.8857
10 A 573.2126 2.5990
11 A 664.5174 1.1982
12 A 723.5646 5.6171
13 A 827.0144 6.0317
14 A 839.2926 0.2214
15 A 866.1392 4.4952
16 A 903.4108 2.0703
17 A 942.7222 0.4506
18 A 976.7980 6.8573
19 A 999.2181 3.8030
20 A 1065.2218 5.9091
21 A 1075.5597 2.8035
22 A 1093.1795 6.1130
23 A 1134.6468 7.2822
24 A 1144.0425 12.4377
25 A 1165.1815 9.2150
26 A 1239.2583 13.5079
27 A 1264.9427 0.2574
28 A 1282.6610 0.4608
29 A 1316.9261 2.0032
30 A 1343.2225 5.0002
31 A 1345.2575 4.8419
32 A 1373.6021 2.7077
33 A 1379.8171 1.5185
34 A 1388.4070 4.2611
35 A 1417.3186 6.3677
36 A 1473.1996 8.4635
37 A 1488.2153 3.6050
38 A 1493.5553 1.4232
39 A 1494.1079 13.4446
40 A 1498.6802 8.4889
41 A 1507.6329 3.0427
42 A 1769.5017 207.9901
43 A 2972.6157 8.3030
44 A 3000.4677 10.5573
45 A 3005.9677 10.2873
46 A 3008.1320 28.1489
47 A 3017.0386 34.0954
48 A 3033.4945 27.6529
49 A 3050.2474 40.6244
50 A 3053.1133 47.3685
51 A 3059.5086 48.5883
52 A 3092.4839 17.3489
53 A 3094.3465 27.4661
54 A 3107.8726 19.3929
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THERE IS MORE TO LIFE THAN INCREASING ITS SPEED. -- GANDHI