WebMO Job Summary
199225: C8H14O (R,S)-2,6-dimethylcyclohexanone, Optimize + Vib Freq - Gaussian
Raw Output
Save Notes
Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ
Method
B3LYP
Stoichiometry
C
8
H
14
O
Symmetry
CS
Basis
6-311+G(2d,p)
RB3LYP Energy
-388.640861103 Hartree
ZPE
0.206002 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-388.425442 Hartree
Enthalpy
-388.424497 Hartree
Free Energy
-388.468728 Hartree
C
v
36.168 cal/mol-K
Entropy
93.090 cal/mol-K
Dipole Moment
3.0580 Debye
Server
class (200288)
CPU time
4734.3 sec
Geometry Sequence Energies
Step
Energy (au)
0
-388.635882665
1
-388.640597906
2
-388.640259527
3
-388.640801875
4
-388.640849592
5
-388.640860450
6
-388.640861103
7
-388.640861103
8
-388.640861103
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.14049
0.07139906101
b
1.57202
0.05243694289
c
0.98267
0.03277834294
Partial Charges
Atom
Symbol
Charge
1
C
-0.227468
2
C
-0.341052
3
C
-0.227468
4
C
0.228909
5
C
0.303201
6
C
0.228909
7
C
-0.551345
8
H
0.136984
9
H
0.114186
10
H
0.137066
11
H
0.085237
12
O
-0.462234
13
H
0.085237
14
C
-0.551345
15
H
0.136984
16
H
0.137066
17
H
0.114186
18
H
0.109993
19
H
0.106448
20
H
0.107091
21
H
0.112976
22
H
0.109993
23
H
0.106448
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A'
76.8744
2.3555
2
A"
127.1761
0.0218
3
A'
192.6666
0.1880
4
A"
200.8635
0.0376
5
A'
236.8475
0.6346
6
A'
275.6088
0.3220
7
A'
308.1412
0.1931
8
A"
316.5885
7.4254
9
A"
365.4910
0.6466
10
A"
403.1699
3.4695
11
A'
417.6401
0.7284
12
A'
537.4387
0.2016
13
A"
591.6590
1.2789
14
A'
675.9915
1.2019
15
A'
759.8168
4.2600
16
A'
837.0486
0.1019
17
A"
852.3470
0.2744
18
A"
865.9756
10.3280
19
A'
907.8804
0.1521
20
A'
959.5726
9.2434
21
A"
982.3415
18.9966
22
A'
989.3042
2.2047
23
A"
1007.3765
6.3755
24
A"
1059.5188
1.4738
25
A"
1081.6977
3.9016
26
A'
1122.8361
1.0341
27
A"
1141.5672
3.7704
28
A'
1142.5567
2.1836
29
A"
1146.5191
27.4798
30
A'
1175.8431
0.0821
31
A"
1247.3732
2.4438
32
A'
1270.5791
0.0040
33
A"
1316.9175
1.0728
34
A'
1324.5528
0.2291
35
A"
1344.3973
3.4556
36
A'
1348.1002
6.6516
37
A"
1377.6705
0.4960
38
A'
1385.2647
0.1097
39
A"
1390.3096
5.9462
40
A"
1417.2566
6.5735
41
A'
1417.5127
6.1856
42
A"
1487.3135
1.1722
43
A'
1488.4757
6.4310
44
A"
1492.9862
0.0052
45
A'
1493.6365
16.4980
46
A'
1497.9742
3.0594
47
A"
1498.6567
12.1560
48
A'
1506.3748
4.9869
49
A'
1766.6119
177.6340
50
A"
2973.0435
4.4399
51
A'
2984.2280
12.4425
52
A'
3000.9849
11.8277
53
A"
3006.1002
24.0364
54
A'
3010.5330
41.7202
55
A"
3033.1657
52.8776
56
A'
3033.6488
5.0514
57
A"
3048.8623
38.2382
58
A'
3049.6960
47.3637
59
A'
3055.0795
48.8871
60
A"
3092.9959
12.2079
61
A'
3093.4567
39.5396
62
A"
3106.0002
0.4320
63
A'
3106.2936
40.2901
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
E PUR SI MUOVE -- GALILEO GALILEI